caa a22 4500 475759923 CHVBK 20180406123547.0 cr unu---uuuuu 170329e20001201xx s 000 0 eng 10.1023/A:1009511622918 doi (NATIONALLICENCE)springer-10.1023/A:1009511622918 Thermodynamic parameters of adsorption of adamantane and its derivatives on graphitized thermal carbon black [Elektronische Daten] [S. Kudryashov, L. Onuchak, A. Voronkov, A. Buryak, I. Moiseev] The adsorption equilibrium constants for adamantane, 1-fluoro-, 1-chloro-, 1,3-difluoro-, 1,3-dichloro-, 1,3-dibromo-, and 1-hydroxyadamantane, and methyl 1-adamantyl ketone were determined by gas chromatography. The results were compared with molecular statistical calculations based on the known atomic-atomic potentials of the interaction of atoms of the sorbate molecule with the C atom of graphitized thermal carbon black (GTCB). The experimental adsorption heats exceed the calculated values by 3-10 kJ mol-1. The reasons for this divergence are discussed. The changes in the adsorption entropy show that the molecules of the studied compounds form a layer of the ideal dimeric gas on the GTCB surface upon adsorption. Plenum Publishing Corporation, 2000 adamantane derivatives nationallicence adsorption nationallicence graphitized thermal carbon black nationallicence molecular statistical calculations nationallicence Kudryashov S. Samara State University, 1 ul. Akad. Pavlova, 443011, Samara, Russian Federation aut Onuchak L. Samara State University, 1 ul. Akad. Pavlova, 443011, Samara, Russian Federation aut Voronkov A. Samara State University, 1 ul. Akad. Pavlova, 443011, Samara, Russian Federation aut Buryak A. Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117915, Moscow, Russian Federation aut Moiseev I. Samara State Technical University, 141 ul. Galaktionovskaya, 443010, Samara, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/12(2000-12-01), 1988-1992 1066-5285 49:12<1988 2000 49 11172 https://doi.org/10.1023/A:1009511622918 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009511622918 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kudryashov S. Samara State University, 1 ul. Akad. Pavlova, 443011, Samara, Russian Federation aut NATIONALLICENCE 700 1- Onuchak L. Samara State University, 1 ul. Akad. Pavlova, 443011, Samara, Russian Federation aut NATIONALLICENCE 700 1- Voronkov A. Samara State University, 1 ul. Akad. Pavlova, 443011, Samara, Russian Federation aut NATIONALLICENCE 700 1- Buryak A. Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117915, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Moiseev I. Samara State Technical University, 141 ul. Galaktionovskaya, 443010, Samara, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/12(2000-12-01), 1988-1992 1066-5285 49:12<1988 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer