caa a22 4500 475760018 CHVBK 20180406123548.0 cr unu---uuuuu 170329e20001201xx s 000 0 eng 10.1023/A:1009515823826 doi (NATIONALLICENCE)springer-10.1023/A:1009515823826 Thermodynamic characteristics of hydrocarbon and chloroalkane adsorption by polymethylsilsesquioxane [Elektronische Daten] [O. Kolyadina, Yu. Murinov, M. Voronkov, Yu. Pozhidaev] Adsorption of n-alkanes (C7H16-C11H24), cyclohexane, benzene, CHCl3, CCl4, and ClCH2CH2Cl by polymethylsilsesquioxane [MeSi(OH)0.4O1.3] n was investigated by inverse gas chromatography in the Henry region. The adsorption isotherms are linear for all adsorbates. The standard changes in the thermodynamic parameters of adsorption were determined. The absence of specific selectivity with respect to aliphatic, cyclic, or aromatic hydrocarbons or chloroalkanes indicates that the adsorbent is chemically homogeneous. Plenum Publishing Corporation, 2000 polymethylsilsesquioxane nationallicence adsorption nationallicence hydrocarbons nationallicence chloroalkanes nationallicence adsorption isotherms nationallicence adsorption energy nationallicence adsorption entropy nationallicence Kolyadina O. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation aut Murinov Yu Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation aut Voronkov M. Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation aut Pozhidaev Yu Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/12(2000-12-01), 2000-2002 1066-5285 49:12<2000 2000 49 11172 https://doi.org/10.1023/A:1009515823826 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009515823826 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kolyadina O. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation aut NATIONALLICENCE 700 1- Murinov Yu Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation aut NATIONALLICENCE 700 1- Voronkov M. Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation aut NATIONALLICENCE 700 1- Pozhidaev Yu Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/12(2000-12-01), 2000-2002 1066-5285 49:12<2000 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer