caa a22 4500 475760093 CHVBK 20180406123548.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1007/BF02494789 doi (NATIONALLICENCE)springer-10.1007/BF02494789 Synthesis of new acyclic aminophosphites and their chelate complexes with rhodium( i ) and palladium( ii ) [Elektronische Daten] [K. Gavrilov, A. Korostylev, O. Bondarev, P. Petrovskii, K. Lyssenko, A. Polosukhin, V. Davankov] New acyclic aminophosphites (RO)2POCH2CH2NMe2 (PN) (R=Et, Pri, or adamantyl) characterized by various steric requirements of the phosphorus center were synthesized. The reactions of the aminophosphites with Pd(COD)Cl2 (COD is 1,5-cyclooctadiene) and [Rh(CO)2Cl]2 afforded the stable chelate mononuclear complexes PdCl2(PN) and RhClCO(PN), respectively. The structures of the resulting compounds were established by1H,13C, and31P NMR and IR spectroscopy, X-ray diffraction analysis, laser and plasma desorption mass spectrometry, X-ray photoelectron spectroscopy, and sedimentation analysis. Kluwer Academic/Plenum Publishers, 2000 acyclic aminophosphites nationallicence palladium complexes nationallicence rhodium complexes nationallicence coordination nationallicence metal chelates nationallicence chelate-forming ligands nationallicence Gavrilov K. S. A. Esenin Ryazan State Pedagogic University, 46 ul. Svobody, 390000, Ryazan, Russian Federation aut Korostylev A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Bondarev O. S. A. Esenin Ryazan State Pedagogic University, 46 ul. Svobody, 390000, Ryazan, Russian Federation aut Petrovskii P. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Lyssenko K. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Polosukhin A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Davankov V. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 533-539 1066-5285 49:3<533 2000 49 11172 https://doi.org/10.1007/BF02494789 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494789 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gavrilov K. S. A. Esenin Ryazan State Pedagogic University, 46 ul. Svobody, 390000, Ryazan, Russian Federation aut NATIONALLICENCE 700 1- Korostylev A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Bondarev O. S. A. Esenin Ryazan State Pedagogic University, 46 ul. Svobody, 390000, Ryazan, Russian Federation aut NATIONALLICENCE 700 1- Petrovskii P. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Lyssenko K. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Polosukhin A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Davankov V. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 533-539 1066-5285 49:3<533 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer