caa a22 4500 475760107 CHVBK 20180406123548.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1007/BF02494787 doi (NATIONALLICENCE)springer-10.1007/BF02494787 New one-step methods for the synthesis of the metallonium dication [Ru(η5-C5Me5)(η5:σ:σ-C5Me3(CH2)2]2+ and its heteroannular analog starting from decamethylruthenoceneand its heteroannular analog starting from decamethylruthenocene [Elektronische Daten] [A. Kamyshova, A. Kreindlin, M. Rybinskaya, P. Petrovskii] The reaction of decamethylruthenocene with oleum or with an oleum—acid (CF3SO3H or CF3CO2H) mixture as well as UV photolysis of a Cp* 2Ru solution in CF3SO3H in the presence of a small amount of oleum afforded two metallonium dications,viz., [Ru(η5-C5Me5)(η5:σ:σ-C5Me3(CH2)2]2+ and [Ru(H2)(η5:σ:-C5Me4CH2)2]2+. The structures of these dications were confirmed by the results of their alkaline hydrolysis and NMR spectra. Kluwer Academic/Plenum Publishers, 2000 decamethylruthenocene nationallicence protonation nationallicence UV photolysis nationallicence metallonium dications nationallicence hydrolysis nationallicence NMR spectra nationallicence Kamyshova A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vaviolova, 117813, Moscow, Russian Federation aut Kreindlin A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vaviolova, 117813, Moscow, Russian Federation aut Rybinskaya M. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vaviolova, 117813, Moscow, Russian Federation aut Petrovskii P. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vaviolova, 117813, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 520-525 1066-5285 49:3<520 2000 49 11172 https://doi.org/10.1007/BF02494787 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494787 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kamyshova A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vaviolova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Kreindlin A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vaviolova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Rybinskaya M. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vaviolova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Petrovskii P. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vaviolova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 520-525 1066-5285 49:3<520 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer