caa a22 4500 475760174 CHVBK 20180406123548.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1007/BF02494771 doi (NATIONALLICENCE)springer-10.1007/BF02494771 Synthesis of high-molecular-weight polyamine by radical polymerization of N,N -diallyl- N -methylamine [Elektronische Daten] [Yu. Vasilieva, N. Kleshcheva, G. Gromova, A. Rebrov, M. Filatova, E. Krut'ko, L. Timofeeva, D. Topchiev] The first synthesis of high-molecular-weight poly(N,N-diallyl-N-methylamine) by thermal (at 30 and 50°C) and photoinduced (at 21 °C) radical polymerization ofN,N-diallyl-N-methylamine (DAMA) in aqueous solution in the presence of an equimolar amount of trifluoroacetic acid (TFA) and by polymerization of the newly synthesized equimolar DAMA·TFA salt is reported. Data of1H NMR spectroscopy indicate that the molecules of the monomer under chosen conditions are in the protonated form. This leads to a decrease in the contribution of the reaction of degradative chain transfer to the monomer and its transformation into effective chain transfer to the monomer. A bimolecular chain termination mechanism was estabilished and the possibility of controlling the polymerization rate and the molecular weight of the polymer was demonstrated. Kluwer Academic/Plenum Publishers, 2000 N,N -diallyl- N -methylamine nationallicence trifluoroacetic acid nationallicence protonation nationallicence radical polymerization nationallicence degradative chain transfer to monomer nationallicence poly( N,N -diallyl- N -methylamine) nationallicence Vasilieva Yu A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut Kleshcheva N. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut Gromova G. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut Rebrov A. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut Filatova M. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut Krut'ko E. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut Timofeeva L. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut Topchiev D. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 431-437 1066-5285 49:3<431 2000 49 11172 https://doi.org/10.1007/BF02494771 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494771 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Vasilieva Yu A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Kleshcheva N. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Gromova G. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Rebrov A. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Filatova M. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Krut'ko E. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Timofeeva L. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Topchiev D. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp, 117912, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 431-437 1066-5285 49:3<431 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer