caa a22 4500 475760220 CHVBK 20180406123548.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1007/BF02494788 doi (NATIONALLICENCE)springer-10.1007/BF02494788 Chemistry of vinylidene complexes [Elektronische Daten] 15. Transmetallation of μ-vinylidene MnPd complexes. Synthesis, X-ray diffraction analysis, and mass spectrometric study of the (η5-C5H5)MnFe2(μ3-C=CHPh)(CO)8 clustercluster [A. Antonova, D. Pogrebnyakov, N. Deykhina, Z. Starikova, F. Dolgushin, A. Belokoń] The reaction of Cp(CO)2Mn=C=CHPh(1) with Pd(PPh3)4 followed by the replacement of the PPh3 ligands by diphosphines Ph2P(CH2)2PPh2 (dppe) or Ph2P(CH2)3PPh2 (dppp) (where dppe is bis(diphenylphosphino)ethane and dppp is 1,3-bis(diphenylphosphino)propane) afforded the binuclear complexes Cp(CO)2MnPd(μ-C=CHPh)(dppe) (2a) and Cp(CO)2MnPd(μ-C=CHPh)(dppp) (2b), respectively. The reactions of2a and2b with Fe2(CO)9 gave the trinuclear complex CpMnFe2(μ3-C=CHPh(CO)3 (3). Competitive transmetallation took the second pathway to yield clusters containing the PdFe3 and PdFe2 cores. Complex3 was also formed in the thermal reaction of compound1 with Fe2(CO)9. Complex3 was studied by IR spectroscopy,1H and13C NMR spectroscopy, mass-spectrometry, and X-ray diffraction analysis. Kluwer Academic/Plenum Publishers, 2000 vinylidene complexes nationallicence heterometallic clusters nationallicence manganese nationallicence iron nationallicence palladium nationallicence mass spectrometry nationallicence X-ray diffraction analysis nationallicence Antonova A. Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, 42 ul. K. Marksa, 660049, Krasnoyarsk, Russian Federation aut Pogrebnyakov D. Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, 42 ul. K. Marksa, 660049, Krasnoyarsk, Russian Federation aut Deykhina N. Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, 42 ul. K. Marksa, 660049, Krasnoyarsk, Russian Federation aut Starikova Z. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Dolgushin F. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Belokoń A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 526-532 1066-5285 49:3<526 2000 49 11172 https://doi.org/10.1007/BF02494788 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494788 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Antonova A. Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, 42 ul. K. Marksa, 660049, Krasnoyarsk, Russian Federation aut NATIONALLICENCE 700 1- Pogrebnyakov D. Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, 42 ul. K. Marksa, 660049, Krasnoyarsk, Russian Federation aut NATIONALLICENCE 700 1- Deykhina N. Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, 42 ul. K. Marksa, 660049, Krasnoyarsk, Russian Federation aut NATIONALLICENCE 700 1- Starikova Z. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Dolgushin F. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Belokoń A. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 526-532 1066-5285 49:3<526 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer