caa a22 4500 475760239 CHVBK 20180406123548.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1007/BF02494772 doi (NATIONALLICENCE)springer-10.1007/BF02494772 Magnetic properties of binuclear high-spin trimethylacetate nickel(II) complexes [Elektronische Daten] [V. Novotortsev, Yu. Rakitin, S. Nefedov, I. Eremenko] The static magnetic susceptibility of mononuclear trimethylacetate nickel complex Ni(NH2Ph)4(OOCCMe3)2 (3) and binuclear complexes Ni2(μ-OH2)(μ-OOCCMe3)2(OOCCMe3)2(dipy)2 (4) and Ni2(μ-OOCCMe3)4py2 (5) was measured in the temperature range of 2-300 K. The magnetic behavior of3 is typical of mononuclear complexes with the Ni11 atom in the octahedral environment. Numerical calculations of the temperature dependence of magnetic susceptibility with inclusion of isotropic exchange interactions (J) and single-ion initial splitting parameters showed that the magnetic behavior of complexes4 and 5 can be interpreted in terms of ferromagnetic (for4) and antiferromagnetic (for5) interactions. Kluwer Academic/Plenum Publishers, 2000 magnetic properties nationallicence ferromagnetism nationallicence antiferromagnetism nationallicence nickel(II) trimethylacetates nationallicence Novotortsev V. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut Rakitin Yu I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Research Center of the Russian Academy of Sciences, 14 ul. Fersmana, 184200, Apatity, Murmansk Region, Russian Federation aut Nefedov S. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut Eremenko I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 438-443 1066-5285 49:3<438 2000 49 11172 https://doi.org/10.1007/BF02494772 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494772 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Novotortsev V. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Rakitin Yu I. V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Research Center of the Russian Academy of Sciences, 14 ul. Fersmana, 184200, Apatity, Murmansk Region, Russian Federation aut NATIONALLICENCE 700 1- Nefedov S. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Eremenko I. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/3(2000-03-01), 438-443 1066-5285 49:3<438 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer