caa a22 4500 475760565 CHVBK 20180406123549.0 cr unu---uuuuu 170329e20001001xx s 000 0 eng 10.1007/BF02496338 doi (NATIONALLICENCE)springer-10.1007/BF02496338 Kinetic analysis of photoelectrochemical hydrogen evolution over p-type silicon in acidic aqueous solutions of electrolytes [Elektronische Daten] [S. Babenko, A. Balakai, A. Lavrushko, Yu. Moskvin, S. Shamaev] The kinetics of photoelectrochemical hydrogen evolution at p-Si single crystals in acidic aqueous solutions of electrolytes under pulse photoexcitation was studied. Despite a low stability of the silicon surface under the experimental conditions, a distinct interrelation between the characteristic time of interfacial charge transfer and stationary current was found. The determination of the characteristic transfer time does not need the detailed elaboration of generation-recombination processes in the semiconductor. The steady-state current density was shown to be determined both for the dark current and photocurrent by the surface charge density. Kluwer Academic/Plenum Publishers, 2000 photoelectrochemistry nationallicence hydrogen evolution nationallicence interfacial charge transfer nationallicence kinetics nationallicence silicon nationallicence Babenko S. Institute of Energy Problems of Chemical Physics (Branch), Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Balakai A. Institute of Energy Problems of Chemical Physics (Branch), Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Lavrushko A. Institute of Energy Problems of Chemical Physics (Branch), Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Moskvin Yu Institute of Energy Problems of Chemical Physics (Branch), Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Shamaev S. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernoglovka, Moscow Region, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/10(2000-10-01), 1707-1711 1066-5285 49:10<1707 2000 49 11172 https://doi.org/10.1007/BF02496338 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02496338 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Babenko S. Institute of Energy Problems of Chemical Physics (Branch), Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Balakai A. Institute of Energy Problems of Chemical Physics (Branch), Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Lavrushko A. Institute of Energy Problems of Chemical Physics (Branch), Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Moskvin Yu Institute of Energy Problems of Chemical Physics (Branch), Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Shamaev S. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernoglovka, Moscow Region, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/10(2000-10-01), 1707-1711 1066-5285 49:10<1707 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer