caa a22 4500 475760816 CHVBK 20180406123550.0 cr unu---uuuuu 170329e20000401xx s 000 0 eng 10.1007/BF02495486 doi (NATIONALLICENCE)springer-10.1007/BF02495486 X-ray spectroscopic study of graphite fluoride (C2F) n intercalated with benzene [Elektronische Daten] [A. Okotrub, A. Antich, L. Bulusheva, V. Paasonen] Samples of intercalated graphite fluoride of the C2F·zR type (R is C6H6) before and after heating to 150 °C in a spectrometer vacuum chamber were studied by X-ray fluorescence spectroscopy. The C-Kα differential spectra of the samples mainly characterizes the electron state of carbon atoms in the benzene molecule inside the C2F matrix. The differential spectrum is distinct from the spectrum of solid benzene by additional maxima, which indicate the interaction between the benzene molecules and the graphite fluoride matrix. Comparative analysis of the spectrum of the heated sample and those of graphite and graphite fluoride (CF) n suggests that the layers of the C2F matrix contain considerable regions of both completely fluorinated and graphite-like regions. Kluwer Academic/Plenum Publishers, 2000 graphite fluoride nationallicence intercalated compounds nationallicence X-ray fluorescence spectroscopy nationallicence electronic structure nationallicence Okotrub A. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 ul. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut Antich A. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 ul. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut Bulusheva L. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 ul. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut Paasonen V. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 ul. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/4(2000-04-01), 709-712 1066-5285 49:4<709 2000 49 11172 https://doi.org/10.1007/BF02495486 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495486 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Okotrub A. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 ul. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut NATIONALLICENCE 700 1- Antich A. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 ul. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut NATIONALLICENCE 700 1- Bulusheva L. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 ul. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut NATIONALLICENCE 700 1- Paasonen V. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 ul. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/4(2000-04-01), 709-712 1066-5285 49:4<709 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer