caa a22 4500 47576093X CHVBK 20180406123550.0 cr unu---uuuuu 170329e20000401xx s 000 0 eng 10.1007/BF02495474 doi (NATIONALLICENCE)springer-10.1007/BF02495474 The formation of formic acid upon low-temperature condensation of CO2−H2 and CO−H2O gas mixtures dissociated in electric discharge [Elektronische Daten] [A. Levanov, A. Gromov, E. Antipenko, V. Lunin] The formation of formic acid in the low-temperature condensation of CO2−H2 and CO−H2O gas mixtures dissociated in electric discharge was investigated. The gas-phase concentrations of H., O., OH., and O2 were measured downstream a microwave discharge in a CO2−H2 mixture. Low-temperature (77 K) condensates formed from CO2−H2 and CO−H2O mixtures were studied by ESR. The formation of formic acid in the CO2−H2 and CO−H2O systems was found to be due to the reactions of H., CO, O., and O2 on the condensate surface. A single mechanism of the formation of formic acid in the CO2−H2 and CO−H2O systems was proposed. Kluwer Academic/Plenum Publishers, 2000 electric discharge in gases nationallicence low-temperature condensation nationallicence formic acid nationallicence hydrogen nationallicence carbon dioxide nationallicence water nationallicence carbon monoxide nationallicence ESR nationallicence frozen radicals nationallicence Levanov A. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Gromov A. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Antipenko E. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Lunin V. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/4(2000-04-01), 642-648 1066-5285 49:4<642 2000 49 11172 https://doi.org/10.1007/BF02495474 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495474 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Levanov A. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Gromov A. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Antipenko E. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Lunin V. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/4(2000-04-01), 642-648 1066-5285 49:4<642 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence SWISSBIB 47576093X BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer