caa a22 4500 475761065 CHVBK 20180406123551.0 cr unu---uuuuu 170329e20000801xx s 000 0 eng 10.1007/BF02495075 doi (NATIONALLICENCE)springer-10.1007/BF02495075 The reaction of 2-aminomethylphenols and their copper(II) complexes with esters of phosphorus acids [Elektronische Daten] [I. Ryzhkina, L. Kudryavtseva, K. Enikeev, V. Morozov, G. Boos, Yu. Sal'nikov] 2-Alkyl- and 2-dialkylaminomethylphenols (AMP) with different hydrophobic substituents at the nitrogen atom and their copper(II) complexes (CAMP) react with the esters of phosphorus acids in aqueous solutions of ethanol in two stages: phosphorylated AMP (PAMP) are formed at the first stage and then hydrolyzed to the corresponding acids. The reactivity of AMP and PAMP significantly decreases when the hydrophobicity and steric hindrances of substituents at the nitrogen atom increase. An inverse dependence was found for CAMP. Kluwer Academic/Plenum Publishers, 2000 2-aminomethylphenols, copper(II), esters of phosphorus acids nationallicence hydrolysis, reactivity, acid-base properties, complex formation nationallicence Ryzhkina I. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Kudryavtseva L. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Enikeev K. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Morozov V. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Boos G. Kazan State University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation aut Sal'nikov Yu Kazan State University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1349-1354 1066-5285 49:8<1349 2000 49 11172 https://doi.org/10.1007/BF02495075 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495075 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ryzhkina I. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Kudryavtseva L. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Enikeev K. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Morozov V. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Boos G. Kazan State University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Sal'nikov Yu Kazan State University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1349-1354 1066-5285 49:8<1349 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer