caa a22 4500 475761081 CHVBK 20180406123551.0 cr unu---uuuuu 170329e20000801xx s 000 0 eng 10.1007/BF02495090 doi (NATIONALLICENCE)springer-10.1007/BF02495090 Electrosynthesis of diazene oxides under oxidation of nitramine anions at Pt in MeCN in the presence of nitrosobenzene [Elektronische Daten] [V. Petrosyan, V. Frolovsky] The electrooxidation of anions of primary nitramine salts RNNO 2 − M+ (R=Me, Et, methoxyfurazanyl; M+=Bu4N+, Li+, Na+) at a Pt anode in the presence of nitrosobenzene in divided and undivided cells was studied by potentio-and amperostatic electrolysis. Solutions of alkali metals and tetrabutylammonium salt in anhydrous MeCN were used as supporting electrolytes. Electrolysis can result in the formation of the corresponding diazene oxide, whose yield depends on the nature of the cation of the supporting electrolyte. In an undivided cell, the yield of diazene oxide increases owing to the regeneration of nitramine anions due to cathodic deprotonation of the nonionized form. The latter is formed by the stabilization of some radical intermediates by the elimination of hydrogen atoms from the components of the medium. Kluwer Academic/Plenum Publishers, 2000 electrosynthesis of diazene oxides nationallicence nitramine anions nationallicence nitrosobenzene nationallicence electrooxidation nationallicence ionic association nationallicence Petrosyan V. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Frolovsky V. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1421-1425 1066-5285 49:8<1421 2000 49 11172 https://doi.org/10.1007/BF02495090 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495090 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Petrosyan V. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Frolovsky V. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1421-1425 1066-5285 49:8<1421 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer