caa a22 4500 475761111 CHVBK 20180406123551.0 cr unu---uuuuu 170329e20000801xx s 000 0 eng 10.1007/BF02495077 doi (NATIONALLICENCE)springer-10.1007/BF02495077 The influence of the structure of tetracoordinate phosphorus acid esters on the catalytic effect of the sodium dodecyl sulfate-hexanol-water ternary reverse micellar system [Elektronische Daten] [L. Zakharova, F. Valeeva, R. Shagidullina, L. Kudryavtseva] The catalytic effect of the sodium dodecyl sulfate-hexanol-water ternary reverse micellar system in the alkaline hydrolysis ofO-alkylO′-aryl chloromethylphosphonates as a function of the substrate structure was studied. The micellar effect is mainly determined by a change in the electronic properties of the substituents, while the hydrophobicity plays a secondary role. The kinetic data were examined in the framework of the pseudo-phase model of micellar catalysis. The rate constants of the reaction in the surface layer and the partition constants of the reactants were calculated. Kluwer Academic/Plenum Publishers, 2000 reverse micelles nationallicence pseudo-phases nationallicence surface layer nationallicence kinetics nationallicence hydrolysis nationallicence phosphonates nationallicence Zakharova L. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Valeeva F. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Shagidullina R. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Kudryavtseva L. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1360-1364 1066-5285 49:8<1360 2000 49 11172 https://doi.org/10.1007/BF02495077 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495077 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zakharova L. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Valeeva F. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Shagidullina R. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Kudryavtseva L. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1360-1364 1066-5285 49:8<1360 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer