caa a22 4500 47576112X CHVBK 20180406123551.0 cr unu---uuuuu 170329e20000801xx s 000 0 eng 10.1007/BF02495095 doi (NATIONALLICENCE)springer-10.1007/BF02495095 Preparation and reactivity of metal-containing monomers 53. Synthesis and stability of a cluster monomer (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 in solution [Elektronische Daten] [V. Ershova, A. Golovin, L. Sheludyakova, P. Semyannikov, S. Pomogailo, A. Pomogailo] The stability of the complex (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 (1), which contains a free unsaturated functional group in the terminal ligand PPh2CH2CH=CH2, with respect to isomerization, chelation of the ligand, and other transformations in solutions was examined. No transformations of complex1 were observed in the course of synthesis from (μ-H)Os3(μ-OCNMe2)(CO)9NMe3 or upon heating in solution. Complex1 as well as complexes (μ-H)Os3(μ-OCNMe2)(CO)9PHPh2 and (μ-H)Os3(μ-OCNMe2)(CO)9PPh3, which were formed as admixtures, were isolated in the solid state and identified by1H,1H-{31P}, and1H-{1H} NMR, IR, and Raman spectroscopy and mass spectrometry. Kluwer Academic/Plenum Publishers, 2000 osmium clusters nationallicence carbamoyl ligand nationallicence allyldiphenylphosphine nationallicence isomerization nationallicence carbonyl(phosphine)osmium nationallicence cluster monomers nationallicence 1H and31P NMR spectroscopy nationallicence Ershova V. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut Golovin A. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut Sheludyakova L. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut Semyannikov P. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut Pomogailo S. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Pomogailo A. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1448-1453 1066-5285 49:8<1448 2000 49 11172 https://doi.org/10.1007/BF02495095 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495095 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ershova V. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut NATIONALLICENCE 700 1- Golovin A. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut NATIONALLICENCE 700 1- Sheludyakova L. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut NATIONALLICENCE 700 1- Semyannikov P. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation aut NATIONALLICENCE 700 1- Pomogailo S. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Pomogailo A. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1448-1453 1066-5285 49:8<1448 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer