caa a22 4500 475761251 CHVBK 20180406123551.0 cr unu---uuuuu 170329e20000801xx s 000 0 eng 10.1007/BF02495080 doi (NATIONALLICENCE)springer-10.1007/BF02495080 Temperature hysteresis phenomena in heterogeneous catalysis [Elektronische Daten] [A. Subbotin, B. Gudkov, V. Yakerson] Temperature hysteresis is observed only in exothermic heterogeneous catalytic reactions (viz., oxidation and methanation of CO or propene hydrogenation) and is absent in the case of endothermic reactions (dehydrogenation of isobutane) or reactions with heat close to zero (viz., 2-butene isomerization). Temperature hysteresis in hydrogenation reactions was discovered for the first time. The concept of local overheating of catalyst active sites caused by poor removal of the reaction heat is proposed to provide a noncontradictory interpretation of the appearance of hysteresis loops. Kluwer Academic/Plenum Publishers, 2000 heterogeneous catalysis nationallicence temperature hysteresis nationallicence oxidation nationallicence hydrogenation nationallicence methanation nationallicence Subbotin A. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Gudkov B. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Yakerson V. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1373-1379 1066-5285 49:8<1373 2000 49 11172 https://doi.org/10.1007/BF02495080 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495080 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Subbotin A. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Gudkov B. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Yakerson V. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1373-1379 1066-5285 49:8<1373 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer