caa a22 4500 475761308 CHVBK 20180406123552.0 cr unu---uuuuu 170329e20000801xx s 000 0 eng 10.1007/BF02495093 doi (NATIONALLICENCE)springer-10.1007/BF02495093 Study of reactions of some halides, cyclopentadienyl dichlorides, and bis(cyclopentadienyl) chlorides of lanthanides with trans -stilbene adducts with alkali metals [PhCHCHPh]·−M+ (M=Li, Na) [Elektronische Daten] [A. Trifonov, E. Fedorova, E. Kirillov, M. Bochkarev, F. Girgsdies, H. Schumann] Reaction of Sml2(THF)2 with metallic lithium andtrans-stilbene in 1:2:2 ratio in DME gives the stilbene complex of divalent samarium (PhCHCHPh)Sm(DME)2. This complex reacts with hydrogen in THF to give SmH2(THF)2 and 1,2-diphenylethane. The reaction with (Me3Si)2NH gives the amide [(Me3Si)2N]2Sm(DME)2 and the reaction with triphenylgermane yields Ph3GeGePh3. Reaction of CpLuCl2(THF)2 with 2 equivalents of [PhCHCHPh]·−Na+ in DME results in the dimerization of stilbene fragments to give anate-complex {Cp2Lu[μ-CH (Ph)CH(Ph)CH(Ph)CH(Ph)]}Na(DME)3. In the reaction of Cp2GdCl with [PhCHCHPh]·−Na+, the known complex Cp3Gd(THF) was isolated as the only lanthanidecontaining product. Kluwer Academic/Plenum Publishers, 2000 lanthanides nationallicence stilbene nationallicence complex nationallicence reactivity nationallicence Trifonov A. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut Fedorova E. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut Kirillov E. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut Bochkarev M. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut Girgsdies F. Institut für anorganische und analitische Chemie, Technische Universität Berlin, 17 Juni Str. 135, D-10623, Berlin 12, Germany aut Schumann H. Institut für anorganische und analitische Chemie, Technische Universität Berlin, 17 Juni Str. 135, D-10623, Berlin 12, Germany aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1436-1439 1066-5285 49:8<1436 2000 49 11172 https://doi.org/10.1007/BF02495093 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02495093 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Trifonov A. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut NATIONALLICENCE 700 1- Fedorova E. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut NATIONALLICENCE 700 1- Kirillov E. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut NATIONALLICENCE 700 1- Bochkarev M. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation aut NATIONALLICENCE 700 1- Girgsdies F. Institut für anorganische und analitische Chemie, Technische Universität Berlin, 17 Juni Str. 135, D-10623, Berlin 12, Germany aut NATIONALLICENCE 700 1- Schumann H. Institut für anorganische und analitische Chemie, Technische Universität Berlin, 17 Juni Str. 135, D-10623, Berlin 12, Germany aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/8(2000-08-01), 1436-1439 1066-5285 49:8<1436 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer