caa a22 4500 475761553 CHVBK 20180406123552.0 cr unu---uuuuu 170329e20000501xx s 000 0 eng 10.1007/BF02494701 doi (NATIONALLICENCE)springer-10.1007/BF02494701 Kinetics of thermal decomposition of hexanitrohexaazaisowurtzitane [Elektronische Daten] [B. Korsounskii, V. Nedel'ko, N. Chukanov, T. Larikova, F. Volk] Thermal decomposition of hexanitrohexaazaisowurtzitane (HNIW) in the solid state and in solution was studied by thermogravimetry, manometry, optical microscopy, and IR spectroscopy. The kinetics of the reaction in the solid state is described by the first-order equation of autocatalysis. The rate constants and activation parameters of HNIW thermal decomposition in the solid state and solution were determined. The content of N2 amounts to approximately half of the gaseous products of HNIW thermolysis. The thermolysis of HNIW and its burning are accompanied by the formation of a condensed residue. During these processes, five of six nitro groups of the HNIW molecule are removed, and one NO2 group remains in the residue, which contains amino groups and no C−H bonds. Kluwer Academic/Plenum Publishers, 2000 nitramines nationallicence hexanitrohexaazaisowurtzitane nationallicence thermal decomposition nationallicence solid state reactions nationallicence kinetics nationallicence Korsounskii B. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Nedel'ko V. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Chukanov N. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Larikova T. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Volk F. Fraunhofer Institut für Chemische Technologie, D-76327, Pfinztal-Berghausen, Germany aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/5(2000-05-01), 812-818 1066-5285 49:5<812 2000 49 11172 https://doi.org/10.1007/BF02494701 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494701 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Korsounskii B. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Nedel'ko V. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Chukanov N. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Larikova T. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Volk F. Fraunhofer Institut für Chemische Technologie, D-76327, Pfinztal-Berghausen, Germany aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/5(2000-05-01), 812-818 1066-5285 49:5<812 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer