caa a22 4500 475761812 CHVBK 20180406123553.0 cr unu---uuuuu 170329e20000201xx s 000 0 eng 10.1007/BF02494691 doi (NATIONALLICENCE)springer-10.1007/BF02494691 Synthesis, crystal structure, and conducting properties of a new molecular conductor (DBTTF)11(TeCl6)4 [Elektronische Daten] [P. Kushch, S. Konovalikhin, G. Shilov, L. Atovmyan, T. Khannanova, R. Lyubovskaya] The structure and conducting properties of a new radical cation salt of dibenzotetrathiafulvalene (DBTTF),viz., (DBTTF)11(TeCl6)4 (1), were studied. According to the X-ray diffraction data, the crystal of1 contains six crystallographically independent DBTTF radical cations alternating with stacks of the (TeCl6)2− anions. At room temperature, the conductivity of the crystals is 15 S cm−1 and it changes exponentially as the temperature decreases. It was found that an increase in the size of the anion in compounds of type1 results in the appearance of interactions between the stacks and in an enhancement of the two-dimensional character of the conductivity. Kluwer Academic/Plenum Publishers, 2000 synthesis nationallicence structure nationallicence dibenzotetrathiofulvalene nationallicence chlorotellurate nationallicence radical cation salt nationallicence conductivity nationallicence Kushch P. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Konovalikhin S. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Shilov G. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Atovmyan L. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Khannanova T. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Lyubovskaya R. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/2(2000-02-01), 372-374 1066-5285 49:2<372 2000 49 11172 https://doi.org/10.1007/BF02494691 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494691 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kushch P. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Konovalikhin S. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Shilov G. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Atovmyan L. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Khannanova T. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Lyubovskaya R. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/2(2000-02-01), 372-374 1066-5285 49:2<372 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer