caa a22 4500 475761952 CHVBK 20180406123554.0 cr unu---uuuuu 170329e20000201xx s 000 0 eng 10.1007/BF02494690 doi (NATIONALLICENCE)springer-10.1007/BF02494690 Synthesis, crystal structure, and spectral studies of the molecular complex of [60]fullerene with chloro(triphenylphosphine)gold(I), C60·2[(Ph3P)AuCl] [Elektronische Daten] [N. Spitsina, V. Gritsenko, O. D'yachenko, B. Safoklov, Yu. Shul'ga, E. Yagubskii] The molecular complex C60·2[(Ph3P)AuCl] (1) was synthesized. The crystal and molecular structure of1 was established by X-ray diffraction analysis. At room temperature, the [60]fullerene molecules in complex1 are ordered due to π—π interactions between C60 and the phenyl rings of the chloro(triphenylphosphine)gold(1) molecules. The satellite structure, which accompanies the Cls photoelectron peak of complex1, is indicative of a partial suppression of a channel of losses due to π→π transition in the phenyl ring. The 1R spectral data indicate that either a charge is absent or the charge transfer to the fullerene molecule is negligible. Kluwer Academic/Plenum Publishers, 2000 chloro(triphenylphosphine)gold(I) nationallicence molecular complex nationallicence [60]fullerene nationallicence X-ray diffraction analysis nationallicence crystal structure nationallicence XPS and IR spectroscopy nationallicence intermolecular interactions nationallicence Spitsina N. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Gritsenko V. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut D'yachenko O. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Safoklov B. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Shul'ga Yu Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Yagubskii E. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/2(2000-02-01), 367-371 1066-5285 49:2<367 2000 49 11172 https://doi.org/10.1007/BF02494690 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494690 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Spitsina N. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Gritsenko V. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- D'yachenko O. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Safoklov B. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Shul'ga Yu Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 700 1- Yagubskii E. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/2(2000-02-01), 367-371 1066-5285 49:2<367 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer