caa a22 4500 475761995 CHVBK 20180406123554.0 cr unu---uuuuu 170329e20000201xx s 000 0 eng 10.1007/BF02494670 doi (NATIONALLICENCE)springer-10.1007/BF02494670 The influence of hydrophobic amines on hydrolysis of bis( p -nitrophenyl) methylphosphonate in micellar solutions of cetylpyridinium bromide [Elektronische Daten] [A. Mirgorodskaya, L. Kudryavtseva, Yu. Zuev, V. Archipov, Z. Idiyatullin, D. Kudryavtsev] The kinetics of hydrolysis of bis(p-nitrophenyl) methylphosphonate in the presence of primary aliphatic amines in aqueous micellar solutions of cetylpyridinium bromide was studied. The reaction proceedsvia two routes, alkaline hydrolysis and amine-catalyzed hydrolysis according to the general basic catalysis mechanism. The contributions of these routes and the catalytic effect of micelles depend on the hydrophobicity of the amines. The formation of different types of micelles was found, and their characteristic parameters were determined by tensiometry and high-resolution1H NMR spectroscopy with a magnetic field pulse gradient. Kluwer Academic/Plenum Publishers, 2000 kinetics nationallicence hydrolysis nationallicence bis( p -nitrophenyl) methylphosphonate nationallicence amines nationallicence micelles nationallicence cetylpyridinium bromide nationallicence 1H NMR spectroscopy nationallicence diffusion nationallicence Mirgorodskaya A. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Kudryavtseva L. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut Zuev Yu Kazan Institute of Biochemistry and Biophysics, Kazan Research Center of the Russian Academy of Sciences, Box 30, 420015, Kazan, Russian Federation aut Archipov V. Kazan State Technological University, 68 ul. K. Marksa, 4200015, Kazan, Russian Federation aut Idiyatullin Z. Kazan State Technological University, 68 ul. K. Marksa, 4200015, Kazan, Russian Federation aut Kudryavtsev D. Kazan State Technological University, 68 ul. K. Marksa, 4200015, Kazan, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/2(2000-02-01), 270-275 1066-5285 49:2<270 2000 49 11172 https://doi.org/10.1007/BF02494670 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494670 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mirgorodskaya A. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Kudryavtseva L. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Zuev Yu Kazan Institute of Biochemistry and Biophysics, Kazan Research Center of the Russian Academy of Sciences, Box 30, 420015, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Archipov V. Kazan State Technological University, 68 ul. K. Marksa, 4200015, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Idiyatullin Z. Kazan State Technological University, 68 ul. K. Marksa, 4200015, Kazan, Russian Federation aut NATIONALLICENCE 700 1- Kudryavtsev D. Kazan State Technological University, 68 ul. K. Marksa, 4200015, Kazan, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/2(2000-02-01), 270-275 1066-5285 49:2<270 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer