caa a22 4500 475762002 CHVBK 20180406123554.0 cr unu---uuuuu 170329e20000201xx s 000 0 eng 10.1007/BF02494694 doi (NATIONALLICENCE)springer-10.1007/BF02494694 Formation of formic and acetic acids by low-temperature condensation of a mixture of methane and water vapor dissociated in MW discharge [Elektronische Daten] [A. Levanov, A. Gromov, E. Antipenko, V. Lunin] Formic and acetic acids are formed by the low-temperature (77 K) condensation of a mixture of methane and water vapor dissociated by MW discharge at a low pressure. The effect of experimental conditions on the yield of HCOOH and AcOH was studied under different experimental conditions. The yields of H, OH, and O2 from MW discharge in the CH4+H2O mixture were determined by ESR in the gas phase under the experimental conditions used to synthesize HCOOH and AcOH. The kinetics of the gas phase reactions in the connecting channel was simulated. The mechanism of formation of HCOOH and AcOH through the interaction of active species from the gas phase on the condensate surface was suggested. Kluwer Academic/Plenum Publishers, 2000 electric discharge in gases nationallicence low-temperature condensation nationallicence formic acid nationallicence acetic acid nationallicence methane nationallicence water nationallicence ESR in gas phase nationallicence hydrogen atoms nationallicence oxygen atoms nationallicence hydroxyl radicals nationallicence Levanov A. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Gromov A. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Antipenko E. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Lunin V. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/2(2000-02-01), 380-383 1066-5285 49:2<380 2000 49 11172 https://doi.org/10.1007/BF02494694 text/html Onlinezugriff via DOI 1 brief-communication jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02494694 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Levanov A. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Gromov A. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Antipenko E. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 700 1- Lunin V. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation aut NATIONALLICENCE 773 0- Russian Chemical Bulletin Kluwer Academic Publishers-Plenum Publishers 49/2(2000-02-01), 380-383 1066-5285 49:2<380 2000 49 11172 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer