caa a22 4500 475763629 CHVBK 20180406123558.0 cr unu---uuuuu 170329e20000601xx s 000 0 eng 10.1007/s003960050558 doi (NATIONALLICENCE)springer-10.1007/s003960050558 Stereochemical aspects of micellar properties of esterified glucoside surfactants in water: apparent molar volume, adiabatic compressibility, and aggregation number [Elektronische Daten] [K. Fukada, M. Kawasaki, T. Seimiya, Y. Abe, M. Fujiwara, K. Ohbu]  The apparent molar volume and the apparent molar adiabatic compressibility of the sugar-based surfactants methyl 6-O-octanoyl-α-d-glucopyranoside (α-MOnG), methyl 6-O-octanoyl-β-d-glucopyranoside (β-MOnG), and octyl β-d-glucoside were measured over a wide concentration range. Also, the aggregation number of their micelles was determined from the Debye plot using static light scattering data. It was found that the micellar aggregation number for α-MOnG is 179 at 35 °C, which is 1.5 times larger than that for β-MOnG, suggesting that the anomerism of the head group influences the packing of the monomers during micelle formation. Springer-Verlag Berlin Heidelberg, 2000 Key words Sugar surfactant nationallicence Anomerism nationallicence Micelle nationallicence Compressibility nationallicence Static light scattering nationallicence Fukada K. Department of Chemistry Graduate School of Science Tokyo Metropolitan University Minamioosawa 1-1 Hachiohji, Tokyo 192-0397 Japan e-mail: fukada-kazuhiro@c.metro-u.ac.jp Tel.: +81-426-772537 Fax: +81-426-772525, JP aut Kawasaki M. Department of Chemistry Graduate School of Science Tokyo Metropolitan University Minamioosawa 1-1 Hachiohji, Tokyo 192-0397 Japan e-mail: fukada-kazuhiro@c.metro-u.ac.jp Tel.: +81-426-772537 Fax: +81-426-772525, JP aut Seimiya T. Department of Chemistry Graduate School of Science Tokyo Metropolitan University Minamioosawa 1-1 Hachiohji, Tokyo 192-0397 Japan e-mail: fukada-kazuhiro@c.metro-u.ac.jp Tel.: +81-426-772537 Fax: +81-426-772525, JP aut Abe Y. Research and Development Headquarters Lion Corporation Hirai 7-13-12 Edogawaku Tokyo 132-0035, Japan, JP aut Fujiwara M. Research and Development Headquarters Lion Corporation Hirai 7-13-12 Edogawaku Tokyo 132-0035, Japan, JP aut Ohbu K. Research and Development Headquarters Lion Corporation Hirai 7-13-12 Edogawaku Tokyo 132-0035, Japan, JP aut https://doi.org/10.1007/s003960050558 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s003960050558 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Fukada K. Department of Chemistry Graduate School of Science Tokyo Metropolitan University Minamioosawa 1-1 Hachiohji, Tokyo 192-0397 Japan e-mail: fukada-kazuhiro@c.metro-u.ac.jp Tel.: +81-426-772537 Fax: +81-426-772525, JP aut NATIONALLICENCE 700 1- Kawasaki M. Department of Chemistry Graduate School of Science Tokyo Metropolitan University Minamioosawa 1-1 Hachiohji, Tokyo 192-0397 Japan e-mail: fukada-kazuhiro@c.metro-u.ac.jp Tel.: +81-426-772537 Fax: +81-426-772525, JP aut NATIONALLICENCE 700 1- Seimiya T. Department of Chemistry Graduate School of Science Tokyo Metropolitan University Minamioosawa 1-1 Hachiohji, Tokyo 192-0397 Japan e-mail: fukada-kazuhiro@c.metro-u.ac.jp Tel.: +81-426-772537 Fax: +81-426-772525, JP aut NATIONALLICENCE 700 1- Abe Y. Research and Development Headquarters Lion Corporation Hirai 7-13-12 Edogawaku Tokyo 132-0035, Japan, JP aut NATIONALLICENCE 700 1- Fujiwara M. Research and Development Headquarters Lion Corporation Hirai 7-13-12 Edogawaku Tokyo 132-0035, Japan, JP aut NATIONALLICENCE 700 1- Ohbu K. Research and Development Headquarters Lion Corporation Hirai 7-13-12 Edogawaku Tokyo 132-0035, Japan, JP aut Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer