caa a22 4500 475764153 CHVBK 20180406123600.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1007/s003960050037 doi (NATIONALLICENCE)springer-10.1007/s003960050037 Different types of water in the film formation process of latex dispersions as detected by solid-state nuclear magnetic resonance spectroscopy [Elektronische Daten] [J. Rottstegge, K. Landfester, M. Wilhelm, H. W. Spiess, C. Heldmann]  The properties of polymer films prepared from latex dispersions are influenced by the drying or film formation process. In order to investigate this process, various systems of aqueous latex dispersions were dried until a specific solid content was reached. The samples investigated were based on vinyl acetate, vinyl acetate/ethylene and pure acrylics employing different surfactants and polyelectrolytes as stabilisers of the dispersions. The role of water in these partially dried films was investigated using 1H and 2H solid-state NMR spectroscopy. Different types of water could be distinguished in the spectra. The drying latex films were found to contain interfacial external water, water at ionic and nonionic groups at surfactants in the polymer/water interface and also water inside the swollen polymer. These different types of water were examined separately using various NMR techniques. Springer-Verlag Berlin Heidelberg, 2000 Key words Latex dispersions nationallicence Film formation nationallicence 1H and 2H solid-state nuclear magnetic resonance nationallicence Water in polymer films nationallicence Rottstegge J. Max-Planck-Institut für Polymerforschung Postfach 3148, D-55021 Mainz, Germany, DE aut Landfester K. Max-Planck-Institut für Polymerforschung Postfach 3148, D-55021 Mainz, Germany, DE aut Wilhelm M. Max-Planck-Institut für Polymerforschung Postfach 3148, D-55021 Mainz, Germany, DE aut Spiess H. W. Max-Planck-Institut für Polymerforschung Postfach 3148, D-55021 Mainz, Germany, DE aut Heldmann C. Clariant GmbH Research and Development D-65926 Frankfurt am Main, Germany, DE aut https://doi.org/10.1007/s003960050037 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s003960050037 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Rottstegge J. Max-Planck-Institut für Polymerforschung Postfach 3148, D-55021 Mainz, Germany, DE aut NATIONALLICENCE 700 1- Landfester K. Max-Planck-Institut für Polymerforschung Postfach 3148, D-55021 Mainz, Germany, DE aut NATIONALLICENCE 700 1- Wilhelm M. Max-Planck-Institut für Polymerforschung Postfach 3148, D-55021 Mainz, Germany, DE aut NATIONALLICENCE 700 1- Spiess H. W. Max-Planck-Institut für Polymerforschung Postfach 3148, D-55021 Mainz, Germany, DE aut NATIONALLICENCE 700 1- Heldmann C. Clariant GmbH Research and Development D-65926 Frankfurt am Main, Germany, DE aut Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer