caa a22 4500 475765095 CHVBK 20180406123603.0 cr unu---uuuuu 170329e20001101xx s 000 0 eng 10.1007/s003960000378 doi (NATIONALLICENCE)springer-10.1007/s003960000378 Polymerisation in supported bilayers [Elektronische Daten] [M. Jung, A. L. German, H. R. Fischer] The intercalation of the twin-tailed amphiphilic dioctadecyldimethylammonium (DODA) ions in smectite clay minerals provides a well-defined supported bilayer system. Polymerisation of styrene in these robust model bilayers allows one to focus on the effect of the constrained medium on the polymerisation process and the polymer. Small-angle X-ray scattering analysis and differential scanning calorimetry data indicated that the polymerisation of styrene in DODA-montmorillonite leads to phase separation between polystyrene and the surfactant matrix. Springer-Verlag Berlin Heidelberg, 2000 Key words Organically modified clay minerals nationallicence Polymerisation nationallicence Supported bilayers nationallicence Dioctadecyldimethylammonium bromide nationallicence Jung M. Laboratory of Polymer Chemistry and Coatings Technology Eindhoven University of Technology P.O. Box 513, 5600 MB Eindhoven The Netherlands e-mail: m.jung@tue.nl Tel.: +31-40-472840 Fax: +31-40-2463966, NL aut German A. L. Laboratory of Polymer Chemistry and Coatings Technology Eindhoven University of Technology P.O. Box 513, 5600 MB Eindhoven The Netherlands e-mail: m.jung@tue.nl Tel.: +31-40-472840 Fax: +31-40-2463966, NL aut Fischer H. R. TNO-TPD Materials Chemistry and Coatings, P.O. Box 595 5600 AN Eindhoven, The Netherlands, NL aut https://doi.org/10.1007/s003960000378 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s003960000378 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Jung M. Laboratory of Polymer Chemistry and Coatings Technology Eindhoven University of Technology P.O. Box 513, 5600 MB Eindhoven The Netherlands e-mail: m.jung@tue.nl Tel.: +31-40-472840 Fax: +31-40-2463966, NL aut NATIONALLICENCE 700 1- German A. L. Laboratory of Polymer Chemistry and Coatings Technology Eindhoven University of Technology P.O. Box 513, 5600 MB Eindhoven The Netherlands e-mail: m.jung@tue.nl Tel.: +31-40-472840 Fax: +31-40-2463966, NL aut NATIONALLICENCE 700 1- Fischer H. R. TNO-TPD Materials Chemistry and Coatings, P.O. Box 595 5600 AN Eindhoven, The Netherlands, NL aut Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer