caa a22 4500 475814924 CHVBK 20180406123807.0 cr unu---uuuuu 170329e20000601xx s 000 0 eng 10.1023/A:1004024218426 doi (NATIONALLICENCE)springer-10.1023/A:1004024218426 Cathodic reduction of 4-nitroso-N,N-dimethylaniline at various electrode materials [Elektronische Daten] [K. Polat, M.L. Aksu, A.T. Pekel] This study is concerned with the cathodic reduction of 4-nitroso-N,N-dimethylaniline to 4-amino-N,N-dimethylaniline in 1.0 M HCl and 1.0 M H2SO4 containing 10% MeOH. The effect of cathode material, supporting electrolyte, electroactive compound concentration, temperature and current density in the electrochemical synthesis of 4-amino-N,N-dimethylaniline were investigated. The best cathode material was tin, which gave a selectivity of 92.7% with a current yield of 90.3% at a current density of 6 mA cm−2. The final electrolysis product was obtained as its respective HCl and H2SO4 salts and their structures were elucidated using spectrochemical techniques. Kluwer Academic Publishers, 2000 4-amino- N , N -dimethylaniline nationallicence cathode material nationallicence dyestuffs nationallicence electrochemical reduction nationallicence nitroso compounds nationallicence photographic developer nationallicence Polat K. Faculty of Science, Department of Chemistry, University of Ankara, Besevler Ankara, Turkey aut Aksu M.L. Faculty of Education, Department of Chemistry, Gazi University, Besevler Ankara, Turkey aut Pekel A.T. Faculty of Science, Department of Chemistry, University of Ankara, Besevler Ankara, Turkey aut Journal of Applied Electrochemistry Kluwer Academic Publishers 30/6(2000-06-01), 733-736 0021-891X 30:6<733 2000 30 10800 https://doi.org/10.1023/A:1004024218426 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1004024218426 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Polat K. Faculty of Science, Department of Chemistry, University of Ankara, Besevler Ankara, Turkey aut NATIONALLICENCE 700 1- Aksu M.L. Faculty of Education, Department of Chemistry, Gazi University, Besevler Ankara, Turkey aut NATIONALLICENCE 700 1- Pekel A.T. Faculty of Science, Department of Chemistry, University of Ankara, Besevler Ankara, Turkey aut NATIONALLICENCE 773 0- Journal of Applied Electrochemistry Kluwer Academic Publishers 30/6(2000-06-01), 733-736 0021-891X 30:6<733 2000 30 10800 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer