caa a22 4500 475815378 CHVBK 20180406123808.0 cr unu---uuuuu 170329e20001201xx s 000 0 eng 10.1023/A:1026597812518 doi (NATIONALLICENCE)springer-10.1023/A:1026597812518 LES of turbulent channel flow of a binary electrolyte [Elektronische Daten] [F. Gurniki, K. Fukagata, S. Zahrai, F.H. Bark] The turbulent diffusion boundary layer in a binary electrolyte was considered at Schmidt numbers of 1, 10 and 100 and exchange current densities between 10−4 A m−2 and 10−2 A m−2. A numerical scheme was developed for efficient investigation of the dynamics by means of large eddy simulations. The methodology was examined by detailed comparisons with documented data from earlier large eddy and direct numerical simulations and good agreement was found. Application of the methodology to electrochemical mass transfer indicated that the exchange current density seems to have negligible effect on the mean concentration profile but it influences the structure of the fluctuating field in a visible manner. Kluwer Academic Publishers, 2000 Butler-Volmer nationallicence forced convection nationallicence high Schmidt number nationallicence large eddy simulation nationallicence near-wall region nationallicence Gurniki F. Faxén Laboratoriet, Royal Institute of Technology, S-10044, Stockholm, Sweden aut Fukagata K. Faxén Laboratoriet, Royal Institute of Technology, S-10044, Stockholm, Sweden aut Zahrai S. ABB, Corporate Research, S-72178, Västerås, Sweden aut Bark F.H. Faxén Laboratoriet, Royal Institute of Technology, S-10044, Stockholm, Sweden aut Journal of Applied Electrochemistry Kluwer Academic Publishers 30/12(2000-12-01), 1335-1343 0021-891X 30:12<1335 2000 30 10800 https://doi.org/10.1023/A:1026597812518 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1026597812518 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Gurniki F. Faxén Laboratoriet, Royal Institute of Technology, S-10044, Stockholm, Sweden aut NATIONALLICENCE 700 1- Fukagata K. Faxén Laboratoriet, Royal Institute of Technology, S-10044, Stockholm, Sweden aut NATIONALLICENCE 700 1- Zahrai S. ABB, Corporate Research, S-72178, Västerås, Sweden aut NATIONALLICENCE 700 1- Bark F.H. Faxén Laboratoriet, Royal Institute of Technology, S-10044, Stockholm, Sweden aut NATIONALLICENCE 773 0- Journal of Applied Electrochemistry Kluwer Academic Publishers 30/12(2000-12-01), 1335-1343 0021-891X 30:12<1335 2000 30 10800 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer