caa a22 4500 475815394 CHVBK 20180406123808.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1023/A:1003984511421 doi (NATIONALLICENCE)springer-10.1023/A:1003984511421 Mass transport in lithium-battery solvents [Elektronische Daten] [Mark Verbrugge, Brian Koch, Eric Schneider] We describe and implement a microelectrode procedure for the determination of important transport properties required for the evaluation of liquid electrolytes used in lithium-based batteries. Three solvents of interest (propylene carbonate, ethylene carbonate, and diethyl carbonate) and two lithium salts (lithium hexafluorophosphate and lithium perchlorate) are investigated. In addition, by combining microelectrode and radiometric analyses, we are able to characterize fully the transport phenomena in the nonaqueous solvent + salt systems. Thus a radiometric technique is used to monitor solvent transport, both under diffusion and current-passage conditions, and the solvent diffusion coefficient is reported as a function of salt concentration. Kluwer Academic Publishers, 2000 batteries nationallicence lithium nationallicence lithium perchlorate nationallicence microelectrode nationallicence radiotracer nationallicence Verbrugge Mark General Motors Advanced Technology Vehicles, 1996 Technology Dr., 48007-7083, Troy, Michigan, USA aut Koch Brian General Motors Advanced Technology Vehicles, 1996 Technology Dr., 48007-7083, Troy, Michigan, USA aut Schneider Eric General Motors Research and Development Center, 30500 Mound Rd., 48090-9055, Warren, MI, USA aut Journal of Applied Electrochemistry Kluwer Academic Publishers 30/3(2000-03-01), 269-275 0021-891X 30:3<269 2000 30 10800 https://doi.org/10.1023/A:1003984511421 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1003984511421 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Verbrugge Mark General Motors Advanced Technology Vehicles, 1996 Technology Dr., 48007-7083, Troy, Michigan, USA aut NATIONALLICENCE 700 1- Koch Brian General Motors Advanced Technology Vehicles, 1996 Technology Dr., 48007-7083, Troy, Michigan, USA aut NATIONALLICENCE 700 1- Schneider Eric General Motors Research and Development Center, 30500 Mound Rd., 48090-9055, Warren, MI, USA aut NATIONALLICENCE 773 0- Journal of Applied Electrochemistry Kluwer Academic Publishers 30/3(2000-03-01), 269-275 0021-891X 30:3<269 2000 30 10800 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer