caa a22 4500 475815807 CHVBK 20180406123809.0 cr unu---uuuuu 170329e20000401xx s 000 0 eng 10.1023/A:1003979117146 doi (NATIONALLICENCE)springer-10.1023/A:1003979117146 Electrochemical investigation of the codeposition of SiC and SiO2 particles with nickel [Elektronische Daten] [P. Nowak, R.P. Socha, M. Kaisheva, J. Fransaer, J.-P. Celis, Z. Stoinov] The use of electrochemical impedance spectroscopy (EIS) for the in situ control of the electrolytic codeposition of Ni/SiO2 and Ni/SiC was investigated. An attempt was made to clarify why silica particles hardly codeposit in comparison to silicon carbide particles. It was found that the presence of SiO2 and SiC particles influences the metal deposition process in different ways. SiC particles that are being embedded in the growing metal layer cause an apparent decrease in the electrode surface area, probably due to blocking off a part of the surface by partly engulfed particles. In the case of SiO2 particles, which embed in the metal matrix to a very limited extent, no blocking was observed. It was found that the presence of particles in the solution causes an apparent increase in the electrode surface area, probably due to increased surface roughness. Kluwer Academic Publishers, 2000 composite coatings nationallicence electrochemical impedance spectroscopy nationallicence nickel electrodeposition nationallicence particle codeposition nationallicence silicon carbide nationallicence Nowak P. Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 1, 30239, Kraków, Poland aut Socha R.P. Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 1, 30239, Kraków, Poland aut Kaisheva M. Faculty of Chemistry, Department of Physical Chemistry, University of Sofia, 1, J. Bourchier Bul., 1126, Sofia, Bulgaria aut Fransaer J. Department of Metallurgy and Materials Engineering, Katholieke Universiteit Leuven, B-3001, Heverlee, Belgium aut Celis J.-P Department of Metallurgy and Materials Engineering, Katholieke Universiteit Leuven, B-3001, Heverlee, Belgium aut Stoinov Z. Central Laboratory of Electric Power Sources, Bulgarian Academy of Sciences, 1126, Sofia, Bulgaria aut Journal of Applied Electrochemistry Kluwer Academic Publishers 30/4(2000-04-01), 429-437 0021-891X 30:4<429 2000 30 10800 https://doi.org/10.1023/A:1003979117146 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1003979117146 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Nowak P. Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 1, 30239, Kraków, Poland aut NATIONALLICENCE 700 1- Socha R.P. Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 1, 30239, Kraków, Poland aut NATIONALLICENCE 700 1- Kaisheva M. Faculty of Chemistry, Department of Physical Chemistry, University of Sofia, 1, J. Bourchier Bul., 1126, Sofia, Bulgaria aut NATIONALLICENCE 700 1- Fransaer J. Department of Metallurgy and Materials Engineering, Katholieke Universiteit Leuven, B-3001, Heverlee, Belgium aut NATIONALLICENCE 700 1- Celis J.-P Department of Metallurgy and Materials Engineering, Katholieke Universiteit Leuven, B-3001, Heverlee, Belgium aut NATIONALLICENCE 700 1- Stoinov Z. Central Laboratory of Electric Power Sources, Bulgarian Academy of Sciences, 1126, Sofia, Bulgaria aut NATIONALLICENCE 773 0- Journal of Applied Electrochemistry Kluwer Academic Publishers 30/4(2000-04-01), 429-437 0021-891X 30:4<429 2000 30 10800 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer