caa a22 4500 475816285 CHVBK 20180406123811.0 cr unu---uuuuu 170329e20000201xx s 000 0 eng 10.1023/A:1003811703854 doi (NATIONALLICENCE)springer-10.1023/A:1003811703854 Barrel zinc electrodeposition from alkaline solution [Elektronische Daten] [M. Wery, J.C. Catonné, J.Y. Hihn] This paper discusses the influence of electrochemical parameters on the concentration-time relationship in an electrolytic zinc deposition reactor using a three-dimensional electrode. The dynamic behaviour of a zinc plating unit is obtained from the fundamental material balance. Two stages are considered: (i) the batch electrolytic reactor, and (ii) the electrolyser surrounded by rinses (i.e., contribution of drag-out). This theoretical approach shows that good control of the operating parameters helps stabilise the zinc electrolyte and, therefore, the properties of the zinc deposits. The aim of the experiments is to investigate, in a statistically designed test program, the effects of the composition of the alkaline zinc electrolyte on cathode efficiency and on the morphologies/textures of the deposits. Kluwer Academic Publishers, 2000 barrel reactor nationallicence deposit texture nationallicence fractional factorial design nationallicence zinc electrodeposition nationallicence Wery M. Laboratoire de Corrosion et de Traitements de Surface, Equipe IUT, Université de Franche-Comté, 30 Avenue de l'Observatoire, BP 1559, 25009, Besançon Cedex, France aut Catonné J.C. Laboratoire d'Electrochimie Industrielle, Conservatoire National des Arts et Métiers, 292 Rue Saint Martin, 75141, Paris Cedex 03, France aut Hihn J.Y. Laboratoire de Corrosion et de Traitements de Surface, Equipe IUT, Université de Franche-Comté, 30 Avenue de l'Observatoire, BP, 1559, 25009, Besançon Cedex, France aut Journal of Applied Electrochemistry Kluwer Academic Publishers 30/2(2000-02-01), 165-172 0021-891X 30:2<165 2000 30 10800 https://doi.org/10.1023/A:1003811703854 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1003811703854 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wery M. Laboratoire de Corrosion et de Traitements de Surface, Equipe IUT, Université de Franche-Comté, 30 Avenue de l'Observatoire, BP 1559, 25009, Besançon Cedex, France aut NATIONALLICENCE 700 1- Catonné J.C. Laboratoire d'Electrochimie Industrielle, Conservatoire National des Arts et Métiers, 292 Rue Saint Martin, 75141, Paris Cedex 03, France aut NATIONALLICENCE 700 1- Hihn J.Y. Laboratoire de Corrosion et de Traitements de Surface, Equipe IUT, Université de Franche-Comté, 30 Avenue de l'Observatoire, BP, 1559, 25009, Besançon Cedex, France aut NATIONALLICENCE 773 0- Journal of Applied Electrochemistry Kluwer Academic Publishers 30/2(2000-02-01), 165-172 0021-891X 30:2<165 2000 30 10800 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer