caa a22 4500 475821688 CHVBK 20180406123820.0 cr unu---uuuuu 170329e20000701xx s 000 0 eng 10.1007/BF02508966 doi (NATIONALLICENCE)springer-10.1007/BF02508966 Intermolecular interactions of a para-nitroaniline molecule in binary solvents [Elektronische Daten] [I. Kuznetsova, Yu. Morozova, O. Bazyl', B. Korolev] The composition of the solvation sheath of a p-nitroaniline molecule in the ground state in mixed solvents (hexane+tetrachloromethane and hexane+isopropyl alcohol) is determined based on the dependence of the ππ*-absorption band shift on the composition of the binary solvent. The interaction of the nitro-group with isopropyl alcohol and water is considered based on results of calculations by the method of intermediate neglect of differential overlap (INDO) and experimental data. It is shown that when the hydrogen bond is formed, the lower singlet level corresponds to the ππ* state. Because of the high rate constant of intercombination conversion, only phosphorescence is characteristic of p-nitroaniline. Kluwer Academic/Plenum Publishers, 2000 Kuznetsova I. aut Morozova Yu aut Bazyl' O. aut Korolev B. aut Russian Physics Journal Kluwer Academic Publishers-Plenum Publishers 43/7(2000-07-01), 608-613 1064-8887 43:7<608 2000 43 11182 https://doi.org/10.1007/BF02508966 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02508966 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kuznetsova I. aut NATIONALLICENCE 700 1- Morozova Yu aut NATIONALLICENCE 700 1- Bazyl' O. aut NATIONALLICENCE 700 1- Korolev B. aut NATIONALLICENCE 773 0- Russian Physics Journal Kluwer Academic Publishers-Plenum Publishers 43/7(2000-07-01), 608-613 1064-8887 43:7<608 2000 43 11182 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer