caa a22 4500 475843649 CHVBK 20180406123907.0 cr unu---uuuuu 170329e20000401xx s 000 0 eng 10.1023/A:1027267023850 doi (NATIONALLICENCE)springer-10.1023/A:1027267023850 Methane oxidative coupling over SrCoO3-based perovskites in periodic regime [Elektronische Daten] [Yu.I. Pyatnitsky, N.I. Ilchenko, L.Yu. Dolgikh, N.V. Pavlenko] The SrCoO3 and AxSr1−xCoO3 (A = Li, Na, K) perovskites are active and stable catalysts for methane coupling reaction performed in a periodic regime where methane and oxygen alternatively react with a catalyst. The temperature-programmed reduction of the catalysts has been made, and a correlation found between catalytic activity and catalyst oxygen reactivity. Experimental and simulation study of reaction kinetics has been performed, and the probable heterogeneous-homogeneous reaction mechanism has been discussed. Kluwer Academic Publishers, 2000 methane coupling nationallicence perovskite catalysts nationallicence unsteady-state catalysis nationallicence kinetic simulation nationallicence Pyatnitsky Yu.I. L.V. Pisarzhevsky Institute of Physical Chemistry, pr. Nauki 31, 03039, Kiev, Ukraine aut Ilchenko N.I. L.V. Pisarzhevsky Institute of Physical Chemistry, pr. Nauki 31, 03039, Kiev, Ukraine aut Dolgikh L.Yu L.V. Pisarzhevsky Institute of Physical Chemistry, pr. Nauki 31, 03039, Kiev, Ukraine aut Pavlenko N.V. L.V. Pisarzhevsky Institute of Physical Chemistry, pr. Nauki 31, 03039, Kiev, Ukraine aut Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 11-12/1-4(2000-04-01), 229-237 1022-5528 11-12:1-4<229 2000 11-12 11244 https://doi.org/10.1023/A:1027267023850 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1027267023850 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Pyatnitsky Yu.I. L.V. Pisarzhevsky Institute of Physical Chemistry, pr. Nauki 31, 03039, Kiev, Ukraine aut NATIONALLICENCE 700 1- Ilchenko N.I. L.V. Pisarzhevsky Institute of Physical Chemistry, pr. Nauki 31, 03039, Kiev, Ukraine aut NATIONALLICENCE 700 1- Dolgikh L.Yu L.V. Pisarzhevsky Institute of Physical Chemistry, pr. Nauki 31, 03039, Kiev, Ukraine aut NATIONALLICENCE 700 1- Pavlenko N.V. L.V. Pisarzhevsky Institute of Physical Chemistry, pr. Nauki 31, 03039, Kiev, Ukraine aut NATIONALLICENCE 773 0- Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 11-12/1-4(2000-04-01), 229-237 1022-5528 11-12:1-4<229 2000 11-12 11244 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer