caa a22 4500 475843665 CHVBK 20180406123907.0 cr unu---uuuuu 170329e20000401xx s 000 0 eng 10.1023/A:1027250520216 doi (NATIONALLICENCE)springer-10.1023/A:1027250520216 Interaction of carbon monoxide with Cu-Pd and Cu-Ni bimetallic clusters [Elektronische Daten] [C.P. Vinod, K.R. Harikumar, G.U. Kulkarni, C.N.R. Rao] Interaction of CO with Cu-Pd and Cu-Ni bimetallic clusters deposited on a ZnO substrate has been investigated by core-level spectroscopy. The surface reactivity of both these alloy clusters increases with the decrease in cluster size, giving rise to dissociative adsorption at small cluster size. The surface reactivity also increases with the increase in Pd or Ni content and the reactivity of the alloy clusters is unlike that of either component metal. Thus, dissociative adsorption occurs on small Cu-Pd clusters unlike on either Cu or Pd clusters of comparable size. The reactivity of the Cu-Ni clusters, on the other hand, falls somewhere between those of Cu and Ni clusters. Kluwer Academic Publishers, 2000 bimetallic clusters nationallicence surface reactivity nationallicence core-level spectroscopy nationallicence Vinod C.P. Chemistry and Physics of Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre For Advanced Scientific Research, Jakkur, 560 064, Bangalore, India E-mail: cnrrao@jncasr.ac.in aut Harikumar K.R. Chemistry and Physics of Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre For Advanced Scientific Research, Jakkur, 560 064, Bangalore, India E-mail: cnrrao@jncasr.ac.in aut Kulkarni G.U. Chemistry and Physics of Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre For Advanced Scientific Research, Jakkur, 560 064, Bangalore, India E-mail: cnrrao@jncasr.ac.in aut Rao C.N.R. Chemistry and Physics of Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre For Advanced Scientific Research, Jakkur, 560 064, Bangalore, India E-mail: cnrrao@jncasr.ac.in aut Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 11-12/1-4(2000-04-01), 293-298 1022-5528 11-12:1-4<293 2000 11-12 11244 https://doi.org/10.1023/A:1027250520216 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1027250520216 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Vinod C.P. Chemistry and Physics of Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre For Advanced Scientific Research, Jakkur, 560 064, Bangalore, India E-mail: cnrrao@jncasr.ac.in aut NATIONALLICENCE 700 1- Harikumar K.R. Chemistry and Physics of Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre For Advanced Scientific Research, Jakkur, 560 064, Bangalore, India E-mail: cnrrao@jncasr.ac.in aut NATIONALLICENCE 700 1- Kulkarni G.U. Chemistry and Physics of Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre For Advanced Scientific Research, Jakkur, 560 064, Bangalore, India E-mail: cnrrao@jncasr.ac.in aut NATIONALLICENCE 700 1- Rao C.N.R. Chemistry and Physics of Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre For Advanced Scientific Research, Jakkur, 560 064, Bangalore, India E-mail: cnrrao@jncasr.ac.in aut NATIONALLICENCE 773 0- Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 11-12/1-4(2000-04-01), 293-298 1022-5528 11-12:1-4<293 2000 11-12 11244 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer