caa a22 4500 47584369X CHVBK 20180406123908.0 cr unu---uuuuu 170329e20000401xx s 000 0 eng 10.1023/A:1027227309738 doi (NATIONALLICENCE)springer-10.1023/A:1027227309738 The new organometallic rhodium-iron homogeneous catalytic system for hydroformylation [Elektronische Daten] [Anna Trzeciak, Ewa Mieczyńska, Józef Ziółkowski] The addition of Fe(CO)5 to the systems with [Rh(acac)(CO)L] complexes (L = PPh3, P(OPh)3, P(NC4H4)3) as catalyst precursors caused the increase of aldehydes yield in 1-hexene hydroformylation reaction (80°C, 10 atm) up to 71%. The IR and 1H NMR measurements confirm the formation of an unstable bimetallic intermediate, [(H)(PPh3)3Rh(µ-CO)2Fe(CO)4], characterized with νCO at 1749 cm−1 and hydrido signal at δ ™15.8 ppm. Kluwer Academic Publishers, 2000 rhodium complexes nationallicence hydroformylation nationallicence bimetallic Rh-Fe complexes nationallicence Trzeciak Anna Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie str., 50-383, Wrocław, Poland aut Mieczyńska Ewa Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie str., 50-383, Wrocław, Poland aut Ziółkowski Józef Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie str., 50-383, Wrocław, Poland aut Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 11-12/1-4(2000-04-01), 461-468 1022-5528 11-12:1-4<461 2000 11-12 11244 https://doi.org/10.1023/A:1027227309738 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1027227309738 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Trzeciak Anna Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie str., 50-383, Wrocław, Poland aut NATIONALLICENCE 700 1- Mieczyńska Ewa Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie str., 50-383, Wrocław, Poland aut NATIONALLICENCE 700 1- Ziółkowski Józef Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie str., 50-383, Wrocław, Poland aut NATIONALLICENCE 773 0- Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 11-12/1-4(2000-04-01), 461-468 1022-5528 11-12:1-4<461 2000 11-12 11244 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer