caa a22 4500 475844068 CHVBK 20180406123908.0 cr unu---uuuuu 170329e20000801xx s 000 0 eng 10.1023/A:1009026131545 doi (NATIONALLICENCE)springer-10.1023/A:1009026131545 Benzylacetate synthesis by oxyacetoxylation of toluene on Pd-Bi binary catalyst [Elektronische Daten] [T. Miyake, A. Hattori, M. Hanaya, S. Tokumaru, H. Hamaji, T. Okada] Benzylacetate synthesis from toluene, acetic acid and oxygen on Pd-Bi binary catalyst was studied in the liquid phase. By incorporation of Bi with Pd, both the activity and selectivity were improved. Especially better stability was obtained with the catalyst having Pd/Bi = 3. Deactivation of the catalyst was investigated in detail by XRD, XPS, TEM, elemental analysis, EPMA and so on. Comparing the used catalyst with the fresh one, it was indicated that the main cause of deactivation was the dissolution of Pd into the reaction mixture from the most outer surface of the catalyst. By adopting proper reaction conditions to prevent the Pd dissolution, the catalyst having Pd/Bi = 3 was suggested to be used as an industrial catalyst. Kluwer Academic Publishers, 2000 oxidation nationallicence oxyacetoxylation nationallicence alloy nationallicence palladium nationallicence bismuth nationallicence benzylacetate nationallicence Miyake T. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut Hattori A. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut Hanaya M. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut Tokumaru S. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut Hamaji H. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut Okada T. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 13/3(2000-08-01), 243-248 1022-5528 13:3<243 2000 13 11244 https://doi.org/10.1023/A:1009026131545 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009026131545 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Miyake T. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut NATIONALLICENCE 700 1- Hattori A. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut NATIONALLICENCE 700 1- Hanaya M. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut NATIONALLICENCE 700 1- Tokumaru S. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut NATIONALLICENCE 700 1- Hamaji H. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut NATIONALLICENCE 700 1- Okada T. Yokkaichi Research Laboratory, Tosoh Corp., 1-8 Kasumi, 510-8540, Yokkaichi, MIE, Japan aut NATIONALLICENCE 773 0- Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 13/3(2000-08-01), 243-248 1022-5528 13:3<243 2000 13 11244 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer