caa a22 4500 475844238 CHVBK 20180406123909.0 cr unu---uuuuu 170329e20000801xx s 000 0 eng 10.1023/A:1009017929727 doi (NATIONALLICENCE)springer-10.1023/A:1009017929727 A new approach for the production of 2,5-furandicarboxylic acid by in situ oxidation of 5-hydroxymethylfurfural starting from fructose [Elektronische Daten] [Martin Kröger, Ulf Prüße, Klaus-Dieter Vorlop] The production of 2,5-furandicarboxylic acid (FDCA) starting with fructose as substrate via acid-catalyzed formation and subsequent oxidation of 5-hydroxymethylfurfural (HMF) was investigated. It was shown that an effective separation of the oxidation catalyst from fructose in combination with extraction and derivatization of formed HMF in methyl isobutyl ketone (MIBK) leads to formation of FDCA as final product. Two systems were developed to realize the concept, one by phase separation with a membrane, the other by encapsulating the oxidation catalyst in silicone beads. Kluwer Academic Publishers, 2000 furandicarboxylic acid nationallicence hydroxymethylfurfural nationallicence methyl isobutyl ketone nationallicence solid acid nationallicence levulinic acid nationallicence Kröger Martin Institute of Technology, Federal Agricultural Research Centre (FAL), Bundesallee 50, 38116, Braunschweig, Germany aut Prüße Ulf Institute of Technology, Federal Agricultural Research Centre (FAL), Bundesallee 50, 38116, Braunschweig, Germany aut Vorlop Klaus-Dieter Institute of Technology, Federal Agricultural Research Centre (FAL), Bundesallee 50, 38116, Braunschweig, Germany aut Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 13/3(2000-08-01), 237-242 1022-5528 13:3<237 2000 13 11244 https://doi.org/10.1023/A:1009017929727 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009017929727 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kröger Martin Institute of Technology, Federal Agricultural Research Centre (FAL), Bundesallee 50, 38116, Braunschweig, Germany aut NATIONALLICENCE 700 1- Prüße Ulf Institute of Technology, Federal Agricultural Research Centre (FAL), Bundesallee 50, 38116, Braunschweig, Germany aut NATIONALLICENCE 700 1- Vorlop Klaus-Dieter Institute of Technology, Federal Agricultural Research Centre (FAL), Bundesallee 50, 38116, Braunschweig, Germany aut NATIONALLICENCE 773 0- Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 13/3(2000-08-01), 237-242 1022-5528 13:3<237 2000 13 11244 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer