caa a22 4500 475844289 CHVBK 20180406123909.0 cr unu---uuuuu 170329e20000801xx s 000 0 eng 10.1023/A:1009086317432 doi (NATIONALLICENCE)springer-10.1023/A:1009086317432 Bifunctional copper catalysts. Part II. Stereoselective synthesis of (-)-menthol starting from (+)-citronellal [Elektronische Daten] [N. Ravasio, N. Poli, R. Psaro, M. Saba, F. Zaccheria] The one-step transformation of (+)-citronellal into (-)-menthol has been realised with yield ∼90% and stereoselectivity up to 80% under mild conditions in the presence of Cu/SiO2 by exploiting the presence of acidic and hydrogenation sites on the catalyst surface, the unusual reducibility of an olefinic bond under these conditions and the chemoselectivity of the process. Kluwer Academic Publishers, 2000 copper catalysts nationallicence bifunctional catalysis nationallicence stereoselectivity nationallicence (-)-menthol nationallicence Ravasio N. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut Poli N. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut Psaro R. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut Saba M. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut Zaccheria F. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 13/3(2000-08-01), 195-199 1022-5528 13:3<195 2000 13 11244 https://doi.org/10.1023/A:1009086317432 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009086317432 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ravasio N. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut NATIONALLICENCE 700 1- Poli N. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut NATIONALLICENCE 700 1- Psaro R. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut NATIONALLICENCE 700 1- Saba M. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut NATIONALLICENCE 700 1- Zaccheria F. Centro C.N.R. CSSCMTBSO, Via Venezian 21, 20133, Milano, Italy aut NATIONALLICENCE 773 0- Topics in Catalysis Kluwer Academic Publishers-Plenum Publishers 13/3(2000-08-01), 195-199 1022-5528 13:3<195 2000 13 11244 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer