caa a22 4500 475844548 CHVBK 20180406123910.0 cr unu---uuuuu 170329e20000501xx s 000 0 eng 10.1023/A:1019192824334 doi (NATIONALLICENCE)springer-10.1023/A:1019192824334 Combining X‐ray absorption with X‐ray diffraction for the structural elucidation of catalysts [Elektronische Daten] [Gopinathan Sankar, John Thomas, C. Catlow] We describe how the combined XAS/XRD technique can provide powerful information on the structures of catalytically active centres. We consider some of the most industrially important catalysts, including Fe‐ZSM‐5, TS‐1, Ti‐zeolite beta, Ti‐MCM‐41 and determine the coordination environment in the active state. In addition, we show how EXAFS information is invaluable as a means for understanding and predicting redox catalytic properties of transition‐metal‐ion‐substituted microporous aluminophosphates - materials which are the best inorganic systems known to date for functionalizing selectively terminal groups of an alkane molecule, in air at moderate temperatures and pressures. Kluwer Academic Publishers, 2000 catalyst design nationallicence selective oxidation of hydrocarbons nationallicence structure of active sites nationallicence shape‐selective catalysis nationallicence Sankar Gopinathan Davy Faraday Research Laboratory, The Royal Institution of Great Britain, 21 Albemarle Street, W1X 4BS, London, UK aut Thomas John Davy Faraday Research Laboratory, The Royal Institution of Great Britain, 21 Albemarle Street, W1X 4BS, London, UK aut Catlow C. Davy Faraday Research Laboratory, The Royal Institution of Great Britain, 21 Albemarle Street, W1X 4BS, London, UK aut Topics in Catalysis Kluwer Academic Publishers 10/3-4(2000-05-01), 255-264 1022-5528 10:3-4<255 2000 10 11244 https://doi.org/10.1023/A:1019192824334 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1019192824334 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sankar Gopinathan Davy Faraday Research Laboratory, The Royal Institution of Great Britain, 21 Albemarle Street, W1X 4BS, London, UK aut NATIONALLICENCE 700 1- Thomas John Davy Faraday Research Laboratory, The Royal Institution of Great Britain, 21 Albemarle Street, W1X 4BS, London, UK aut NATIONALLICENCE 700 1- Catlow C. Davy Faraday Research Laboratory, The Royal Institution of Great Britain, 21 Albemarle Street, W1X 4BS, London, UK aut NATIONALLICENCE 773 0- Topics in Catalysis Kluwer Academic Publishers 10/3-4(2000-05-01), 255-264 1022-5528 10:3-4<255 2000 10 11244 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer