caa a22 4500 475847687 CHVBK 20180406123919.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1023/A:1009081218955 doi (NATIONALLICENCE)springer-10.1023/A:1009081218955 Further Aspects of the Chemistry of the Dirhenium Complexes [(triphos)Re(μ-X)3Re(triphos)] n + (n=1 or 0), Where triphos=CH3C(CH2PPh2)3 and X=Cl or Br [Elektronische Daten] [Michael Siwajek, Yan Ding, Phillip Fanwick, Richard Walton] The dirhenium(II) complexes [Re2(μ-X)3(triphos)2]O3SCF3 (X=Cl or Br) have been prepared by anion exchange reactions. These salts show well defined simple electron-transfer redox chemistry (two reversible one-electron oxidations and two one-electron reductions) but the [Re(μ-X)3Re] unit is remarkably stable to reactions with donor molecules such as monodentate tertiary phosphines which can often induce cleavage of M-X-M bridges. The crystallographic characterization of these two salts show that Re-Re bonds are not present, the Re...Re distances being 3.274(1) Å for X=Cl and 3.277(1) Å for X=Br. Plenum Publishing Corporation, 2000 rhenium nationallicence dirhenium complexes nationallicence rhenium-rhenium multiple bonds nationallicence tripodal phosphine ligands nationallicence crystal structures nationallicence Siwajek Michael aut Ding Yan Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut Fanwick Phillip Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut Walton Richard Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/1(2000-03-01), 243-251 1040-7278 11:1<243 2000 11 10876 https://doi.org/10.1023/A:1009081218955 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009081218955 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Siwajek Michael aut NATIONALLICENCE 700 1- Ding Yan Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut NATIONALLICENCE 700 1- Fanwick Phillip Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut NATIONALLICENCE 700 1- Walton Richard Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/1(2000-03-01), 243-251 1040-7278 11:1<243 2000 11 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer