caa a22 4500 475847768 CHVBK 20180406123919.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1023/A:1009008630342 doi (NATIONALLICENCE)springer-10.1023/A:1009008630342 A Novel Cluster Consisting of Seven Fused MX6 Octahedra, Li14(THF)8[Ni7Cl17(μ-formamidinate)3(μ-Cl)]2 [Elektronische Daten] [F. Cotton, Carlos Murillo, Isabel Pascual] When a THF solution made from equimolar amounts of methyllithium and N,N′-bispentafluorophenyl formamidine, C6F5NC(H)N(H)C6F5, was added to a suspension of NiCl2 in THF and the mixture refluxed for 12 h, a bright yellow-green solution was formed, from which a bright green crystalline compound was obtained in >60% yield upon partial evaporation of the solvent. This compound, Li14(THF)8[Ni7Cl17(μ-formamidinate)3(μ-Cl)]2·9.4THF, crystallizes in the tetragonal space group P4 2/mnm (No. 136) with Z=2. The core consists of two Ni7 units bridged by two Cl atoms. Plenum Publishing Corporation, 2000 nickel cluster nationallicence fluorinated formamidine nationallicence crystal structure nationallicence Cotton F. Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A & M University, P.O. Box 30012, 77842-3012, College Station, TX aut Murillo Carlos Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A & M University, P.O. Box 30012, 77842-3012, College Station, TX aut Pascual Isabel Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A & M University, P.O. Box 30012, 77842-3012, College Station, TX aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/1(2000-03-01), 87-94 1040-7278 11:1<87 2000 11 10876 https://doi.org/10.1023/A:1009008630342 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009008630342 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Cotton F. Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A & M University, P.O. Box 30012, 77842-3012, College Station, TX aut NATIONALLICENCE 700 1- Murillo Carlos Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A & M University, P.O. Box 30012, 77842-3012, College Station, TX aut NATIONALLICENCE 700 1- Pascual Isabel Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A & M University, P.O. Box 30012, 77842-3012, College Station, TX aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/1(2000-03-01), 87-94 1040-7278 11:1<87 2000 11 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer