caa a22 4500 475847776 CHVBK 20180406123919.0 cr unu---uuuuu 170329e20000301xx s 000 0 eng 10.1023/A:1009048311686 doi (NATIONALLICENCE)springer-10.1023/A:1009048311686 Synthesis of Co3(CO)7(μ-η3-Allyl)(μ3-X) Complexes (X=S,Se) and Structure of the Selenium Derivative [Elektronische Daten] [László Markó, Giuliana Gervasio, Domenica Marabello, Gá Szalontai] The complexes Co3(CO)9(μ 3-X) (X=S,Se) can be reduced to the corresponding anionic species [Co3(CO)9(μ 3-X)]−, which react with allyl bromide to give Co3(CO)7(μ-η 3-C3H5)(μ 3-X) (X=S,Se). These are the first two cobalt complexes containing the bridging μ-η 3-allyl ligand. The structure of the selenium complex was determined by X-ray crystallography. Crystal data for Co3(CO)7(μ-η 3-C3H5)(μ 3-Se) are as follows: space group P21/c, a=9.051(2) Å, b=8.102(2) Å, c=21.27(4) Å, β=93.82(3)°, Z=4, and R=0.0565 for 2491 observed reflections. Plenum Publishing Corporation, 2000 tricobalt clusters nationallicence μ - η 3-allyl nationallicence selenium nationallicence sulfur nationallicence Markó László Petrochemistry, Hungarian Academy of Sciences, P.O. Box 158, H-8201, Veszprém, Hungary aut Gervasio Giuliana Dipartimento di Chimica I.F.M., Università di Torino, I-10125, Torino, Italy aut Marabello Domenica Dipartimento di Chimica I.F.M., Università di Torino, I-10125, Torino, Italy aut Szalontai Gá Central Laboratory, University of Veszprém, P.O. Box 158, H-8201, Veszprém, Hungary aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/1(2000-03-01), 29-38 1040-7278 11:1<29 2000 11 10876 https://doi.org/10.1023/A:1009048311686 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009048311686 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Markó László Petrochemistry, Hungarian Academy of Sciences, P.O. Box 158, H-8201, Veszprém, Hungary aut NATIONALLICENCE 700 1- Gervasio Giuliana Dipartimento di Chimica I.F.M., Università di Torino, I-10125, Torino, Italy aut NATIONALLICENCE 700 1- Marabello Domenica Dipartimento di Chimica I.F.M., Università di Torino, I-10125, Torino, Italy aut NATIONALLICENCE 700 1- Szalontai Gá Central Laboratory, University of Veszprém, P.O. Box 158, H-8201, Veszprém, Hungary aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/1(2000-03-01), 29-38 1040-7278 11:1<29 2000 11 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer