caa a22 4500 47584789X CHVBK 20180406123919.0 cr unu---uuuuu 170329e20000901xx s 000 0 eng 10.1023/A:1009003717104 doi (NATIONALLICENCE)springer-10.1023/A:1009003717104 Synthesis of a Mo-Ru/Carbon Nanocomposite Using (η-C7H7)(OC)2MoRu(CO)2(η-C5H5) as a Single-Source Molecular Precursor [Elektronische Daten] [Krzysztof Kwiatkowski, C. Lukehart, Oliver Murphy, Stanley Simpson] Degradation of a (η-C7H7)(OC)2MoRu(CO)2(η-C5H5)/carbon powder composite under appropriate thermal conditions affords a nanocomposite containing crystalline nanoclusters of Mo-Ru alloy highly dispersed on the carbon support. The alloy nanoparticles have an average diameter of 2.2 nm and crystallize as a fully disordered fcc lattice having a cell constant of 4.09 Å. When tested as an cathode catalyst in a direct methanol fuel cell, this nanocomposite shows significant methanol tolerance but affords current production too low to be of practical importance. Plenum Publishing Corporation, 2000 nanocomposite nationallicence metal alloy nanocrystals nationallicence metal/carbon composite nationallicence MoRu clusters nationallicence Kwiatkowski Krzysztof Department of Chemistry, Vanderbilt University, 37235, Nashville, Tennessee aut Lukehart C. Department of Chemistry, Vanderbilt University, 37235, Nashville, Tennessee aut Murphy Oliver Lynntech, Inc., 7610 Eastmark Drive, Suite 105, 77840, College Station, Texas aut Simpson Stanley Lynntech, Inc., 7610 Eastmark Drive, Suite 105, 77840, College Station, Texas aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/3(2000-09-01), 449-459 1040-7278 11:3<449 2000 11 10876 https://doi.org/10.1023/A:1009003717104 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009003717104 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kwiatkowski Krzysztof Department of Chemistry, Vanderbilt University, 37235, Nashville, Tennessee aut NATIONALLICENCE 700 1- Lukehart C. Department of Chemistry, Vanderbilt University, 37235, Nashville, Tennessee aut NATIONALLICENCE 700 1- Murphy Oliver Lynntech, Inc., 7610 Eastmark Drive, Suite 105, 77840, College Station, Texas aut NATIONALLICENCE 700 1- Simpson Stanley Lynntech, Inc., 7610 Eastmark Drive, Suite 105, 77840, College Station, Texas aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/3(2000-09-01), 449-459 1040-7278 11:3<449 2000 11 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer