caa a22 4500 475847911 CHVBK 20180406123920.0 cr unu---uuuuu 170329e20000901xx s 000 0 eng 10.1023/A:1009047432125 doi (NATIONALLICENCE)springer-10.1023/A:1009047432125 Electrochemical Studies of Water-Soluble Palladium Nanoparticles [Elektronische Daten] [Shaowei Chen, Kui Huang] Aqueous-soluble monolayer-protected palladium nanoparticles were synthesized by hydrogen reduction of Pd(II) in a water solution. The particles were then further functionalized by incorporating multiple copies of mercapto derivatives of viologen into the particle protecting monolayers. The electrochemistry of the viologen moieties with the particles dissolved in solution or immobilized onto electrode surfaces was carefully studied using various electrochemical techniques. The particle molecular capacitance was evaluated by rotating-disk-electrode voltammetry and the electron-transfer rate constant of the particle-bound viologen moieties was estimated by impedance measurements. Plenum Publishing Corporation, 2000 palladium nationallicence nanoparticles nationallicence viologen nationallicence electrochemistry nationallicence impedance nationallicence electron-transfer kinetics nationallicence self-assembled monolayer nationallicence Chen Shaowei Department of Chemistry, Southern Illinois University, 62901-4409, Carbondale, Illinois aut Huang Kui Department of Chemistry, Southern Illinois University, 62901-4409, Carbondale, Illinois aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/3(2000-09-01), 405-422 1040-7278 11:3<405 2000 11 10876 https://doi.org/10.1023/A:1009047432125 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009047432125 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Chen Shaowei Department of Chemistry, Southern Illinois University, 62901-4409, Carbondale, Illinois aut NATIONALLICENCE 700 1- Huang Kui Department of Chemistry, Southern Illinois University, 62901-4409, Carbondale, Illinois aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/3(2000-09-01), 405-422 1040-7278 11:3<405 2000 11 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer