caa a22 4500 475847954 CHVBK 20180406123920.0 cr unu---uuuuu 170329e20001201xx s 000 0 eng 10.1023/A:1009092612840 doi (NATIONALLICENCE)springer-10.1023/A:1009092612840 Synthesis and Structure of a Molybdenum-Cobalt Bimetallic Carbide Cluster [N(PPh3)2][Mo3Co3(μ6-C)(μ-CO)3(CO)15] Bearing Only Carbonyl Ligands [Elektronische Daten] [Satoshi Kamiguchi, Teiji Chihara] The reaction of a trinuclear cobalt cluster [ClCCo3(CO)9] with [Mo(CO)3(CH3CN)3] gave a molybdenum-cobalt bimetallic cluster complex [Mo3Co3(μ 6-C)(μ-CO)3(CO)15]−. The cluster anion has a carbide-centered Mo3Co3 octahedral metal core, where the three molybdenum and three cobalt atoms are placed in facial positions. The six metal atoms are coordinated by only carbonyl ligands. The cluster is suitable for a model of heterogeneous desulfurization catalysts. Plenum Publishing Corporation, 2000 molybdenum nationallicence cobalt nationallicence bimetallic nationallicence metal carbonyl nationallicence carbido cluster nationallicence Kamiguchi Satoshi RIKEN (The Institute of Physical and Chemical Research), Wako-shi, 351-0198, Saitama, Japan aut Chihara Teiji RIKEN (The Institute of Physical and Chemical Research), Wako-shi, 351-0198, Saitama, Japan aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/4(2000-12-01), 483-492 1040-7278 11:4<483 2000 11 10876 https://doi.org/10.1023/A:1009092612840 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009092612840 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Kamiguchi Satoshi RIKEN (The Institute of Physical and Chemical Research), Wako-shi, 351-0198, Saitama, Japan aut NATIONALLICENCE 700 1- Chihara Teiji RIKEN (The Institute of Physical and Chemical Research), Wako-shi, 351-0198, Saitama, Japan aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/4(2000-12-01), 483-492 1040-7278 11:4<483 2000 11 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer