caa a22 4500 475847997 CHVBK 20180406123920.0 cr unu---uuuuu 170329e20001201xx s 000 0 eng 10.1023/A:1009096713749 doi (NATIONALLICENCE)springer-10.1023/A:1009096713749 Reactions of the Dirhenium(II) Complexes Re2X4(μ-dppm)2 (X=Cl, Br; dppm=Ph2PCH2PPh2) with Isocyanides. XXII. A Comparison of Mixed Carbonyl-Isocyanide Complexes with Those Formed by Re2Cl4(μ-dcpm)2 (dcpm=Cy2PCH2PCy2) [Elektronische Daten] [Michael Siwajek, Richard Walton] The reactions of the electron-rich triply bonded dirhenium(II) complex Re2Cl4(μ-dcpm)2 (dcpm=Cy2PCH2PCy2) with the isocyanide ligands XylNC (Xyl=2,6-dimethylphenyl) and t-BuNC afford the complexes Re2Cl4(μ-dcpm)2(CNXyl) and Re2Cl4(μ-dcpm)2(CN-t-Bu)2 which in turn react with CO to give salts of the [Re2Cl3(μ-dcpm)2(CO)2(CNXyl)]+ and [Re2Cl3(μ-dcpm)2(CN-t-Bu)2(CO)]+ cations which exist in different isomeric forms. This chemistry is compared with that developed previously for the analogous complexes derived from Re2Cl4(μ-dppm)2. Plenum Publishing Corporation, 2000 rhenium nationallicence dirhenium complexes nationallicence rhenium-rhenium multiple bonds nationallicence isocyanide ligands nationallicence carbonyl ligand nationallicence structural isomers nationallicence Siwajek Michael Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut Walton Richard Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/4(2000-12-01), 511-518 1040-7278 11:4<511 2000 11 10876 https://doi.org/10.1023/A:1009096713749 text/html Onlinezugriff via DOI 1 article jats NATIONALLICENCE 856 40 https://doi.org/10.1023/A:1009096713749 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Siwajek Michael Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut NATIONALLICENCE 700 1- Walton Richard Department of Chemistry, Purdue University, 47907-1393, West Lafayette, Indiana aut NATIONALLICENCE 773 0- Journal of Cluster Science Kluwer Academic Publishers-Plenum Publishers 11/4(2000-12-01), 511-518 1040-7278 11:4<511 2000 11 10876 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer