caa a22 4500 477049745 CHVBK 20180405111338.0 cr unu---uuuuu 170330e19961201xx s 000 0 eng 10.1007/BF00249931 doi (NATIONALLICENCE)springer-10.1007/BF00249931 Electrochemical reduction of Fe( ii ) ions on different solid electrodes in fused ZnCl2-2NaCl mixture [Elektronische Daten] [Y. Castrillejo, A. Martinez, M. Vega, P. Sanchez Batanero] The electrodeposition of Fe(II) in ZnCl2-2NaCl melt at 450°C was studied at molybdenum and tungsten electrodes and the results are compared with those obtained at glassy carbon in previous work. The kinetics of the electrodeposition and electrocrystallization of iron were studied, showing that the process is quasireversible, and the values of the kinetic parameters κ° and α were obtained. Mass transport towards the electrode is a simple diffusion process and the diffusion coefficient was obtained by applying different electrochemical techniques. Potential step measurements indicate that instantaneous nucleation and growth phenomena play a part in the overall process. Chapman & Hall, 1996 Castrillejo Y. Dpto. de Química Analítica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena s/n, 47005, Valladolid, Spain aut Martinez A. Dpto. de Química Analítica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena s/n, 47005, Valladolid, Spain aut Vega M. Dpto. de Química Analítica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena s/n, 47005, Valladolid, Spain aut Sanchez Batanero P. Dpto. de Química Analítica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena s/n, 47005, Valladolid, Spain aut Journal of Applied Electrochemistry Kluwer Academic Publishers 26/12(1996-12-01), 1279-1285 0021-891X 26:12<1279 1996 26 10800 https://doi.org/10.1007/BF00249931 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00249931 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Castrillejo Y. Dpto. de Química Analítica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena s/n, 47005, Valladolid, Spain aut NATIONALLICENCE 700 1- Martinez A. Dpto. de Química Analítica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena s/n, 47005, Valladolid, Spain aut NATIONALLICENCE 700 1- Vega M. Dpto. de Química Analítica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena s/n, 47005, Valladolid, Spain aut NATIONALLICENCE 700 1- Sanchez Batanero P. Dpto. de Química Analítica, Facultad de Ciencias, Universidad de Valladolid, Prado de la Magdalena s/n, 47005, Valladolid, Spain aut NATIONALLICENCE 773 0- Journal of Applied Electrochemistry Kluwer Academic Publishers 26/12(1996-12-01), 1279-1285 0021-891X 26:12<1279 1996 26 10800 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer