caa a22 4500 477050247 CHVBK 20180405111339.0 cr unu---uuuuu 170330e19960301xx s 000 0 eng 10.1007/BF00242102 doi (NATIONALLICENCE)springer-10.1007/BF00242102 Electrodeposition of titanium diboride from fused salts [Elektronische Daten] [M. Makyta, V. Daněk, G. Haarberg, J. Thonstad] Electrodeposition of TiB2 has been performed in cryolite-based electrolytes at 960°C and in KF-KCl melts at 800°C. As electroactive species either boron oxide and titanium oxide or potassium tetrafluoroborate and potassium hexafluorotitanate were used. Preparation of coatings from cryolite-based electrolytes containing K2TiF6 and KBF4 was not successful. Coatings prepared from cryolite-based electrolytes containing B2O3 and TiO2 were not coherent. Owing to the relatively high temperature both types of electrolytes undergo thermal decomposition. Electrolysis in potassium fluoride-chloride electrolytes containing KBF4 and K2TiF6 provides coherent coatings with good adhesion to the substrate. Chapman & Hall, 1996 Makyta M. Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, SK-842 36, Bratislava, Slovakia aut Daněk V. Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, SK-842 36, Bratislava, Slovakia aut Haarberg G. Department of Electrochemistry, The Norwegian Institute of Technology, Sem Saelandsvei 6, N-7034, Trondheim, Norway aut Thonstad J. Department of Electrochemistry, The Norwegian Institute of Technology, Sem Saelandsvei 6, N-7034, Trondheim, Norway aut Journal of Applied Electrochemistry Kluwer Academic Publishers 26/3(1996-03-01), 319-324 0021-891X 26:3<319 1996 26 10800 https://doi.org/10.1007/BF00242102 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00242102 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Makyta M. Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, SK-842 36, Bratislava, Slovakia aut NATIONALLICENCE 700 1- Daněk V. Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, SK-842 36, Bratislava, Slovakia aut NATIONALLICENCE 700 1- Haarberg G. Department of Electrochemistry, The Norwegian Institute of Technology, Sem Saelandsvei 6, N-7034, Trondheim, Norway aut NATIONALLICENCE 700 1- Thonstad J. Department of Electrochemistry, The Norwegian Institute of Technology, Sem Saelandsvei 6, N-7034, Trondheim, Norway aut NATIONALLICENCE 773 0- Journal of Applied Electrochemistry Kluwer Academic Publishers 26/3(1996-03-01), 319-324 0021-891X 26:3<319 1996 26 10800 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer