caa a22 4500 477051065 CHVBK 20180405111340.0 cr unu---uuuuu 170330e19960801xx s 000 0 eng 10.1007/BF00683743 doi (NATIONALLICENCE)springer-10.1007/BF00683743 Electrochemical generation of ferrate Part I: Dissolution of an iron wool bed anode [Elektronische Daten] [A. Denvir, D. Pletcher] The preparation of ferrate by the anodic dissolution of iron in 10m NaOH using a membrane cell with an iron wool anode is described. It is shown that the current efficiency drops from an initial value of 45-60% to ∼25% during a 2-3 h electrolysis. This is shown to be due to a change in the iron anode surface, probably the composition, structure and/or thickness of surface films. The influence of cell current as well as NaOH concentration and temperature on the current efficiency is described. The kinetics of the reactions of ferrate with water, alcohols and phenol have also been investigated and it is shown that some organics (methanol, ethanediol and phenol) undergo complete oxidation to CO2 and H2O even at room temperature. Chapman & Hall, 1996 Denvir A. Department of Chemistry, The University, 5017 1BJ, Southampton, Great Britain aut Pletcher D. Department of Chemistry, The University, 5017 1BJ, Southampton, Great Britain aut Journal of Applied Electrochemistry Kluwer Academic Publishers 26/8(1996-08-01), 815-822 0021-891X 26:8<815 1996 26 10800 https://doi.org/10.1007/BF00683743 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00683743 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Denvir A. Department of Chemistry, The University, 5017 1BJ, Southampton, Great Britain aut NATIONALLICENCE 700 1- Pletcher D. Department of Chemistry, The University, 5017 1BJ, Southampton, Great Britain aut NATIONALLICENCE 773 0- Journal of Applied Electrochemistry Kluwer Academic Publishers 26/8(1996-08-01), 815-822 0021-891X 26:8<815 1996 26 10800 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer