caa a22 4500 477051588 CHVBK 20180405111340.0 cr unu---uuuuu 170330e19960201xx s 000 0 eng 10.1007/BF00364061 doi (NATIONALLICENCE)springer-10.1007/BF00364061 Effect of magnetic charging of Ni on electrolytic codeposition of Zn with Ni particles [Elektronische Daten] [R. Tacken, P. Jiskoot, L. Janssen] Composite materials with unique properties can be produced by codepositing an inert phase during a cathodic metal deposition process. The feasibility of codeposition is mainly determined by the interaction of the inert phase and the cathodically deposited metal. When both the inert phase and the cathode or the cathodically deposited metal are ferromagnetic substances, codeposition can be promoted by magnetizing the inert phase prior to codeposition. Codeposition of Zn with Ni particles on a steel cathode from a weakly acidic zinc chloride based bath was investigated. The increased interaction between the magnetically remanent Ni particles and the steel cathode resulted in substantially higher percentages of Ni included in the deposit layer, especially at low concentrations of Ni particles in the bath. The model of Guglielmi, modified for conducting particles, proved to be valid; the value of adsorption parameter k ad changed with magnetic remanency. Cathodic Zn deposition efficiency decreased with increasing concentration of Ni particles in solution and increasing Ni content in the deposit. The principle outlined can also be applied to systems with nonferromagnetic inert phases by coating these with ferromagnetic substances. Chapman & Hall, 1996 Tacken R. Department of Chemical Engineering, Laboratory of Instrumental Analysis, Eindhoven University of Technology, PO Box 513, 5600, MB Eindhoven, The Netherlands aut Jiskoot P. Department of Chemical Engineering, Laboratory of Instrumental Analysis, Eindhoven University of Technology, PO Box 513, 5600, MB Eindhoven, The Netherlands aut Janssen L. Department of Chemical Engineering, Laboratory of Instrumental Analysis, Eindhoven University of Technology, PO Box 513, 5600, MB Eindhoven, The Netherlands aut Journal of Applied Electrochemistry Kluwer Academic Publishers 26/2(1996-02-01), 129-134 0021-891X 26:2<129 1996 26 10800 https://doi.org/10.1007/BF00364061 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00364061 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Tacken R. Department of Chemical Engineering, Laboratory of Instrumental Analysis, Eindhoven University of Technology, PO Box 513, 5600, MB Eindhoven, The Netherlands aut NATIONALLICENCE 700 1- Jiskoot P. Department of Chemical Engineering, Laboratory of Instrumental Analysis, Eindhoven University of Technology, PO Box 513, 5600, MB Eindhoven, The Netherlands aut NATIONALLICENCE 700 1- Janssen L. Department of Chemical Engineering, Laboratory of Instrumental Analysis, Eindhoven University of Technology, PO Box 513, 5600, MB Eindhoven, The Netherlands aut NATIONALLICENCE 773 0- Journal of Applied Electrochemistry Kluwer Academic Publishers 26/2(1996-02-01), 129-134 0021-891X 26:2<129 1996 26 10800 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer