caa a22 4500 477061117 CHVBK 20180405111400.0 cr unu---uuuuu 170330e19960701xx s 000 0 eng 10.1007/BF00210288 doi (NATIONALLICENCE)springer-10.1007/BF00210288 Observation of DMSO and CH3S(O)OH from the gas phase reaction between DMS and OH [Elektronische Daten] [S. Sørensen, H. Falbe-Hansen, M. Mangoni, J. Hjorth, N. Jensen] Products and mechanisms have been investigated for the reactions between dimethylsulfide (DMS) and dimethylsulfoxide (DMSO) and the hydroxyl radical (OH) in the presence of NOx. All of the experiments were performed in a 480 L reaction chamber, applying Fourier transform infrared spectroscopy (FT-IR) and ion chromatography as the analytical techniques. In addition to the sulfur containing products that are known to be produced from the gas phase reaction between DMS and OH (SO2, dimethylsulfone, methylsulfonyl peroxynitrate, methanesulfonic acid, H2SO4), DMSO and methanesulfinic acid (CH3S(O)OH) were also observed as products. Only SO2, DMSO2 and methylsulfonyl peroxynitrate were found as sulfur containing products in the reaction between DMSO and OH. Based on these new results we propose a mechanism for the atmospheric oxidation of DMS and DMSO by OH radical. Kluwer Academic Publishers, 1996 products nationallicence mechanism nationallicence gas phase nationallicence dimethylsulfide nationallicence hydroxyl radical nationallicence dimethylsulfoxide nationallicence methanesulfinic acid nationallicence air nationallicence Sørensen S. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut Falbe-Hansen H. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut Mangoni M. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut Hjorth J. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut Jensen N. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut Journal of Atmospheric Chemistry Kluwer Academic Publishers 24/3(1996-07-01), 299-315 0167-7764 24:3<299 1996 24 10874 https://doi.org/10.1007/BF00210288 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF00210288 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sørensen S. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut NATIONALLICENCE 700 1- Falbe-Hansen H. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut NATIONALLICENCE 700 1- Mangoni M. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut NATIONALLICENCE 700 1- Hjorth J. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut NATIONALLICENCE 700 1- Jensen N. European Commission, Joint Research Centre, Environment Institute, TP 272, I-21020, Ispra (VA), Italy aut NATIONALLICENCE 773 0- Journal of Atmospheric Chemistry Kluwer Academic Publishers 24/3(1996-07-01), 299-315 0167-7764 24:3<299 1996 24 10874 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer