caa a22 4500 477080731 CHVBK 20180405111449.0 cr unu---uuuuu 170330e19960801xx s 000 0 eng 10.1007/BF02113868 doi (NATIONALLICENCE)springer-10.1007/BF02113868 Bowker Michael Catalysis Research Centre, Department of Chemistry, University of Reading, Whiteknights Park, RG6 6AD, Reading, UK aut Active sites in methanol oxidation on Cu(110) determined by STM and molecular beam measurements [Elektronische Daten] [Michael Bowker] STM has been combined with molecular beam rate measurements to gain an understanding of the oxidative dehydrogenation of methanol to produce formaldehyde, both at the macroscopic and microscopic level. From this a model of the reaction is developed where the methanol initial reacts at very few active oxygen sites located at the short sides of oxygen islands on the Cu(110) surface. Such sites are very much rarer on a surface which is saturated with 0.5 monolayers of oxygen and the reaction rate is initially very low, but shows autocatalytic behaviour, rising in time as vacancies are created in the oxygen layer. J.C. Baltzer AG, Science Publishers, 1996 active site nationallicence catalysis nationallicence selective oxidation nationallicence methanol nationallicence copper nationallicence Topics in Catalysis Baltzer Science Publishers, Baarn/Kluwer Academic Publishers 3/3-4(1996-08-01), 461-468 1022-5528 3:3-4<461 1996 3 11244 https://doi.org/10.1007/BF02113868 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/BF02113868 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Bowker Michael Catalysis Research Centre, Department of Chemistry, University of Reading, Whiteknights Park, RG6 6AD, Reading, UK aut NATIONALLICENCE 773 0- Topics in Catalysis Baltzer Science Publishers, Baarn/Kluwer Academic Publishers 3/3-4(1996-08-01), 461-468 1022-5528 3:3-4<461 1996 3 11244 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer